KEGG   REACTION: R01652
Entry
R01652                      Reaction                               
Definition
4-Methyl-2-oxopentanoate + CO2 <=> (2S)-2-Isopropyl-3-oxosuccinate
Equation
C00233 + C00011 <=> C04236
Comment
spontaneous (following EC 1.1.1.85 or R04426 reaction)
Reaction class
RC00577  C00233_C04236
Enzyme
1.1.1.85
Pathway
rn00290  Valine, leucine and isoleucine biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01210  2-Oxocarboxylic acid metabolism
Module
M00432  Leucine biosynthesis, 2-oxoisovalerate => 2-oxoisocaproate
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.1  Acting on the CH-OH group of donors
   1.1.1  With NAD+ or NADP+ as acceptor
    1.1.1.85
     R01652  4-Methyl-2-oxopentanoate + CO2 <=> (2S)-2-Isopropyl-3-oxosuccinate
Other DBs
RHEA: 25081
LinkDB

KEGG   RCLASS: RC00577
Entry
RC00577                     RClass                                 
Definition
C1b-C1c:*-C6a:C1c+C5a-C1c+C5a
Reactant pair
C00233_C04236
Related class
Reaction
R01652
Enzyme
1.1.1.85
Pathway
rn00290  Valine, leucine and isoleucine biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01210  2-Oxocarboxylic acid metabolism
RModule
RM001  2-Oxocarboxylic acid chain extension by tricarboxylic acid pathway

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