KEGG   REACTION: R05301
Entry
R05301                      Reaction                               
Name
penicillin-N,2-oxoglutarate:oxygen oxidoreductase (ring-expanding)
Definition
Penicillin N + 2-Oxoglutarate + Oxygen <=> Deacetoxycephalosporin C + Succinate + CO2 + H2O
Equation
C06564 + C00026 + C00007 <=> C06565 + C00042 + C00011 + C00001
Reaction class
RC01322  C06564_C06565
Enzyme
1.14.20.1
Pathway
rn00311  Penicillin and cephalosporin biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00673  Cephamycin C biosynthesis, aminoadipate + cycteine + valine => cephamycin C
Orthology
K12744  deacetoxycephalosporin-C synthase [EC:1.14.20.1]
Other DBs
RHEA: 20751
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