KEGG   REACTION: R05442
Entry
R05442                      Reaction                               
Name
o-xylene,ferredoxin:oxygen oxidoreductase (methyl-hydroxylating)
Definition
o-Xylene + Oxygen + 2 Reduced ferredoxin + 2 H+ <=> 2-Methylbenzyl alcohol + 2 Oxidized ferredoxin + H2O
Equation
Comment
xylene monooxygenase
Reaction class
RC00269  C07212_C07213
Enzyme
Pathway
rn00622  Xylene degradation
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
Module
M00537  Xylene degradation, xylene => methylbenzoate
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.15  With reduced iron-sulfur protein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.15.26
     R05442  o-Xylene + Oxygen + 2 Reduced ferredoxin + 2 H+ <=> 2-Methylbenzyl alcohol + 2 Oxidized ferredoxin + H2O
Orthology
K15757  toluene methyl-monooxygenase [EC:1.14.15.26]
K15758  toluene methyl-monooxygenase electron transfer component [EC:1.18.1.3]
LinkDB

KEGG   RCLASS: RC00269
Entry
RC00269                     RClass                                 
Definition
C1a-C1b:*-O1a:C8y-C8y
Reactant pair
Related class
Reaction
Enzyme
1.14.11.6       1.14.11.80      1.14.13.122     1.14.13.-       
1.14.14.-       1.14.15.25      1.14.15.26      1.17.7.2        
1.17.9.1        1.17.98.2
Pathway
rn00622  Xylene degradation
rn00623  Toluene degradation
rn00626  Naphthalene degradation
rn00860  Porphyrin metabolism
rn00980  Metabolism of xenobiotics by cytochrome P450
rn01057  Biosynthesis of type II polyketide products
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
RModule
RM003  Methyl to carboxyl conversion on aromatic ring
Orthology
K10616  p-cymene methyl-monooxygenase [EC:1.14.15.25]
K13097  methylcytosine dioxygenase [EC:1.14.11.80]
K13600  chlorophyllide a oxygenase [EC:1.14.13.122]
K15757  toluene methyl-monooxygenase [EC:1.14.15.26]
K15758  toluene methyl-monooxygenase electron transfer component [EC:1.18.1.3]
K15760  toluene monooxygenase system protein A [EC:1.14.13.236 1.14.13.-]
K15761  toluene monooxygenase system protein B [EC:1.14.13.236 1.14.13.-]
K15762  toluene monooxygenase system ferredoxin subunit
K15763  toluene monooxygenase system protein D [EC:1.14.13.236 1.14.13.-]
K15764  toluene monooxygenase system protein E [EC:1.14.13.236 1.14.13.-]
K15765  toluene monooxygenase electron transfer component [EC:1.18.1.3]
K15768  p-toluenesulfonate methyl-monooxygenase oxygenase component TsaM [EC:1.14.13.-]
K15769  p-toluenesulfonate methyl-monooxygenase reductase component TsaB [EC:1.5.1.-]
K17709  cytochrome P450 family 2 subfamily B6 [EC:1.14.14.-]
K18010  7-hydroxymethyl chlorophyll a reductase [EC:1.17.7.2]
K18293  p-cymene methyl-monooxygenase electron transfer component [EC:1.18.1.3]

DBGET integrated database retrieval system