KEGG   REACTION: R07463
Entry
R07463                      Reaction                               
Name
glycine:oxygen oxidoreductase
Definition
Glycine + Oxygen <=> Iminoglycine + Hydrogen peroxide
Equation
C00037 + C00007 <=> C15809 + C00027
Reaction class
RC01788  C00037_C15809
RC02755  C00007_C00027
Enzyme
1.4.3.19
Pathway
rn00730  Thiamine metabolism
rn01100  Metabolic pathways
rn01240  Biosynthesis of cofactors
Module
M00895  Thiamine biosynthesis, prokaryotes, AIR (+ DXP/glycine) => TMP/TPP
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.4  Acting on the CH-NH2 group of donors
   1.4.3  With oxygen as acceptor
    1.4.3.19
     R07463  Glycine + Oxygen <=> Iminoglycine + Hydrogen peroxide
Orthology
K03153  glycine oxidase [EC:1.4.3.19]
Other DBs
RHEA: 33346
LinkDB

KEGG   REACTION: R10246
Entry
R10246                      Reaction                               
Name
L-tyrosine 4-methylphenol-lyase (2-iminoacetate-forming)
Definition
L-Tyrosine + S-Adenosyl-L-methionine + Reduced acceptor <=> Iminoglycine + 4-Cresol + 5'-Deoxyadenosine + L-Methionine + Acceptor
Equation
C00082 + C00019 + C00030 <=> C15809 + C01468 + C05198 + C00073 + C00028
Comment
radical SAM
Reaction class
RC00021  C00019_C00073
RC01434  C00082_C01468
RC03095  C00082_C15809
Enzyme
4.1.99.19
Pathway
rn00730  Thiamine metabolism
rn01100  Metabolic pathways
rn01240  Biosynthesis of cofactors
Module
M00127  Thiamine biosynthesis, prokaryotes, AIR (+ DXP/tyrosine) => TMP/TPP
Brite
Enzymatic reactions [BR:br08201]
 4. Lyase reactions
  4.1  Carbon-carbon lyases
   4.1.99  Other carbon-carbon lyases
    4.1.99.19
     R10246  L-Tyrosine + S-Adenosyl-L-methionine + Reduced acceptor <=> Iminoglycine + 4-Cresol + 5'-Deoxyadenosine + L-Methionine + Acceptor
Orthology
K03150  2-iminoacetate synthase [EC:4.1.99.19]
Other DBs
RHEA: 26364
LinkDB

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