KEGG   REACTION: R08111
Entry
R08111                      Reaction                               
Name
3-fluorocyclohexadiene-cis,cis-1,2-diol-1-carboxylate:NAD+oxidoreductase (decarboxylating)
Definition
3-Fluorocyclohexadiene-cis,cis-1,2-diol-1-carboxylate + NAD+ <=> 3-Fluorocatechol + NADH + CO2 + H+
Equation
C16478 + C00003 <=> C16472 + C00004 + C00011 + C00080
Reaction class
RC00001  C00003_C00004
RC01326  C16472_C16478
Enzyme
1.3.1.25
Pathway
rn00364  Fluorobenzoate degradation
rn01120  Microbial metabolism in diverse environments
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.3  Acting on the CH-CH group of donors
   1.3.1  With NAD+ or NADP+ as acceptor
    1.3.1.25
     R08111  3-Fluorocyclohexadiene-cis,cis-1,2-diol-1-carboxylate + NAD+ <=> 3-Fluorocatechol + NADH + CO2 + H+
Orthology
K05783  dihydroxycyclohexadiene carboxylate dehydrogenase [EC:1.3.1.25 1.3.1.-]
LinkDB

KEGG   RCLASS: RC01326
Entry
RC01326                     RClass                                 
Definition
C1y-C8y:*-*:C1z+C2y+O1a-C8y+C8y+O1a
C1z-C8y:C6a-*:C1y+C2x+O1a-C8y+C8x+O1a
Reactant pair
C02923_C06720    C16472_C16478
Related class
Reaction
R05309 R08111
Enzyme
1.3.1.25        1.3.1.-
Pathway
rn00364  Fluorobenzoate degradation
rn00622  Xylene degradation
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
RModule
RM005  Dihydroxylation of aromatic ring, type 1a (dioxygenase and decarboxylating dehydrogenase reactions)
Orthology
K05783  dihydroxycyclohexadiene carboxylate dehydrogenase [EC:1.3.1.25 1.3.1.-]

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