KEGG   REACTION: R08666
Entry
R08666                      Reaction                               
Name
4-methylthiobutanaldoxime,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (adding cysteine)
Definition
4-Methylthiobutanaldoxime + L-Cysteine + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> S-(4-Methylthiobutylthiohydroximoyl)-L-cysteine + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Equation
C17241 + C00097 + C03024 + C00007 <=> C17242 + C03161 + 2 C00001
Reaction class
RC02210  C17241_C17242
Enzyme
1.14.14.43
Pathway
rn00966  Glucosinolate biosynthesis
rn01110  Biosynthesis of secondary metabolites
rn01210  2-Oxocarboxylic acid metabolism
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.43
     R08666  4-Methylthiobutanaldoxime + L-Cysteine + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> S-(4-Methylthiobutylthiohydroximoyl)-L-cysteine + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Orthology
K12156  (methylthio)alkanaldoxime N-monooxygenase [EC:1.14.14.43]
LinkDB

KEGG   RCLASS: RC02210
Entry
RC02210                     RClass                                 
Definition
C2b-C2c:*-S2a:C1b+N2b-C1b+N2b
Reactant pair
C02937_C16518    C04350_C17238    C04353_C17238
C16075_C17237    C17237_C19714    C17241_C17242
C19714_C21622
Related class
Reaction
R08168 R08653 R08659 R08666 R10670 R10672 R11737
Enzyme
1.14.14.43      1.14.14.45      1.14.-.-
Pathway
rn00380  Tryptophan metabolism
rn00966  Glucosinolate biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01210  2-Oxocarboxylic acid metabolism
RModule
RM030  Glucosinolate synthesis
Orthology
K11818  aromatic aldoxime N-monooxygenase [EC:1.14.14.45]
K12156  (methylthio)alkanaldoxime N-monooxygenase [EC:1.14.14.43]

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