KEGG   REACTION: R09567
Entry
R09567                      Reaction                               
Name
dichlorochromopyrrolate,NADH:oxygen 2,5-oxidoreductase (dichloroarcyriaflavin A-forming)
Definition
3,4-Bis(7-chloroindol-3-yl)pyrrole-2,5-dicarboxylate + 4 Oxygen + 4 NADH + 4 H+ <=> Dichloroarcyriaflavin A + 2 CO2 + 6 H2O + 4 NAD+
Equation
C19698 + 4 C00007 + 4 C00004 + 4 C00080 <=> C19699 + 2 C00011 + 6 C00001 + 4 C00003
Reaction class
RC00001  C00003_C00004
RC02569  C19698_C19699
Enzyme
1.13.12.17
Pathway
rn00404  Staurosporine biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00789  Rebeccamycin biosynthesis, tryptophan => rebeccamycin
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.13  Acting on single donors with incorporation of molecular oxygen (oxygenases)
   1.13.12  With incorporation of one atom of oxygen (internal monooxygenases or internal mixed-function oxidases)
    1.13.12.17
     R09567  3,4-Bis(7-chloroindol-3-yl)pyrrole-2,5-dicarboxylate + 4 Oxygen + 4 NADH + 4 H+ <=> Dichloroarcyriaflavin A + 2 CO2 + 6 H2O + 4 NAD+
Orthology
K19886  flavin-dependent monooxygenase RebC [EC:1.13.12.17]
K19887  cytochrome P450 RebP [EC:1.13.12.17]
Other DBs
RHEA: 27317
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