KEGG REACTION: R10033

REACTION: R10033

Entry

R10033                      Reaction

Definition

N,N-Dihydroxy-L-valine <=> (E)-2-Methylpropanal oxime + CO2 + H2O

Equation

C20314 <=> C03219 + C00011 + C00001

Comment

the last step of three-step reaction (see R08663, R10031+R10032+R10033)

Reaction class

RC03009

C03219_C20314

Enzyme

1.14.14.38 1.14.14.39

Pathway

rn00460

Cyanoamino acid metabolism

rn01100

Metabolic pathways

rn01110

Biosynthesis of secondary metabolites

Brite

Enzymatic reactions [BR:br08201]
1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.38
     R10033  N,N-Dihydroxy-L-valine <=> (E)-2-Methylpropanal oxime + CO2 + H2O
    1.14.14.39
     R10033  N,N-Dihydroxy-L-valine <=> (E)-2-Methylpropanal oxime + CO2 + H2O

Orthology

K13401

valine N-monooxygenase [EC:1.14.14.38]

K14984

isoleucine N-monooxygenase [EC:1.14.14.39]

Other DBs

RHEA:

30502

LinkDB

RCLASS: RC03009

Entry

RC03009                     RClass

Definition

C1c-C2b:C6a-*:C1c+N1c-C1c+N2b
N1c-N2b:O1b-*:C1c+O1b-C2b+O1b

Reactant pair

C03219_C20314 C19491_C20311

Related class

Reaction

R10029 R10033