KEGG   REACTION: R10319
Entry
R10319                      Reaction                               
Name
8-O-methylsterigmatocystin,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (aflatoxin-B forming)
Definition
O-Methylsterigmatocystin + 2 [Reduced NADPH---hemoprotein reductase] + 2 Oxygen <=> Aflatoxin B1 + 2 [Oxidized NADPH---hemoprotein reductase] + H2O + Methanol + CO2
Equation
C03686 + 2 C03024 + 2 C00007 <=> C06800 + 2 C03161 + C00001 + C00132 + C00011
Reaction class
RC03113  C03686_C06800
Enzyme
1.14.14.117
Pathway
rn00254  Aflatoxin biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00937  Aflatoxin biosynthesis, malonyl-CoA => aflatoxin B1
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.117
     R10319  O-Methylsterigmatocystin + 2 [Reduced NADPH---hemoprotein reductase] + 2 Oxygen <=> Aflatoxin B1 + 2 [Oxidized NADPH---hemoprotein reductase] + H2O + Methanol + CO2
Orthology
K17651  aflatoxin B synthase [EC:1.14.14.117]
Other DBs
RHEA: 35762
LinkDB

KEGG   RCLASS: RC03113
Entry
RC03113                     RClass                                 
Definition
C1x-C8x:*-*:C1x+C5x-C8x+C8y
C1x-C8x:C8y+*-*+C8x:C1x-C8x
C5x-C8y:O5x+*-*+O2a:C1x+C8y-C8x+C8y
C8y-C8y:C1x+*-*+O5x:C8y+C8y-C8y+C8y
C8y-C8y:O6a+*-*+C8x:C8y+O7x-C8y+O2x
O5x-O5x:C5x+*-*+C8y:*-*
Reactant pair
C03686_C06800    C03944_C16753
Related class
Reaction
R10319 R10320
Enzyme
1.14.14.117
Pathway
rn00254  Aflatoxin biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Orthology
K17651  aflatoxin B synthase [EC:1.14.14.117]

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