KEGG   REACTION: R10936
Entry
R10936                      Reaction                               
Name
3-(methylthio)acryloyl-CoA hydratase
Definition
3-(Methylthio)acryloyl-CoA + 2 H2O <=> Acetaldehyde + Methanethiol + CoA + CO2
Equation
C20955 + 2 C00001 <=> C00084 + C00409 + C00010 + C00011
Comment
four-step reaction (see R10945+R10946+R10947+R06973)
Reaction class
RC00004  C00010_C20955
RC03306  C00084_C20955
RC03307  C00409_C20955
Enzyme
4.2.1.155
Pathway
rn00920  Sulfur metabolism
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
Module
M00990  Dimethylsulfoniopropionate (DMSP) degradation, demethylation pathway, DMSP => methanethiol
Brite
Enzymatic reactions [BR:br08201]
 4. Lyase reactions
  4.2  Carbon-oxygen lyases
   4.2.1  Hydro-lyases
    4.2.1.155
     R10936  3-(Methylthio)acryloyl-CoA + 2 H2O <=> Acetaldehyde + Methanethiol + CoA + CO2
Orthology
K20036  (methylthio)acryloyl-CoA hydratase [EC:4.2.1.155]
Other DBs
RHEA: 45147
LinkDB

KEGG   REACTION: R10945
Entry
R10945                      Reaction                               
Name
3-(methylthio)acryloyl-CoA hydratase;
3-hydroxy-3-(methylthio)propanoyl-CoA hydro-lyase
Definition
3-(Methylthio)acryloyl-CoA + H2O <=> 3-Hydroxy-3-(methylthio)propanoyl-CoA
Equation
C20955 + C00001 <=> C20968
Comment
the first step of four-step reaction (see R10936, R10945+R10946+R10947+R06973)
Reaction class
RC03311  C20955_C20968
Enzyme
4.2.1.155
Brite
Enzymatic reactions [BR:br08201]
 4. Lyase reactions
  4.2  Carbon-oxygen lyases
   4.2.1  Hydro-lyases
    4.2.1.155
     R10945  3-(Methylthio)acryloyl-CoA + H2O <=> 3-Hydroxy-3-(methylthio)propanoyl-CoA
Other DBs
RHEA: 45151
LinkDB

KEGG   REACTION: R10946
Entry
R10946                      Reaction                               
Name
3-hydroxy-3-(methylthio)propanoyl-CoA methanethiol-lyase
Definition
3-Hydroxy-3-(methylthio)propanoyl-CoA <=> 3-Oxopropionyl-CoA + Methanethiol
Equation
C20968 <=> C05989 + C00409
Comment
the second step of four-step reaction (see R10936, R10945+R10946+R10947+R06973)
Reaction class
RC03312  C05989_C20968
RC03313  C00409_C20968
Enzyme
4.2.1.155
Brite
Enzymatic reactions [BR:br08201]
 4. Lyase reactions
  4.2  Carbon-oxygen lyases
   4.2.1  Hydro-lyases
    4.2.1.155
     R10946  3-Hydroxy-3-(methylthio)propanoyl-CoA <=> 3-Oxopropionyl-CoA + Methanethiol
Other DBs
RHEA: 45155
LinkDB

KEGG   REACTION: R10947
Entry
R10947                      Reaction                               
Name
3-oxopropionyl-CoA hydrolase
Definition
3-Oxopropionyl-CoA + H2O <=> 3-Oxopropanoate + CoA
Equation
C05989 + C00001 <=> C00222 + C00010
Comment
the third step of four-step reaction (see R10936, R10945+R10946+R10947+R06973)
Reaction class
RC00004  C00010_C05989
RC00014  C00222_C05989
Enzyme
4.2.1.155
Brite
Enzymatic reactions [BR:br08201]
 4. Lyase reactions
  4.2  Carbon-oxygen lyases
   4.2.1  Hydro-lyases
    4.2.1.155
     R10947  3-Oxopropionyl-CoA + H2O <=> 3-Oxopropanoate + CoA
Other DBs
RHEA: 45159
LinkDB

KEGG   REACTION: R06973
Entry
R06973                      Reaction                               
Name
3-oxopropanoate carboxy-lyase
Definition
3-Oxopropanoate <=> Acetaldehyde + CO2
Equation
C00222 <=> C00084 + C00011
Comment
malonate semialdehyde decarboxylase
(methylthio)acryloyl-CoA hydratase, the last step of four-step reaction (see R10936, R10945+R10946+R10947+R06973)
Reaction class
RC01775  C00084_C00222
Enzyme
4.1.1.-         4.2.1.155
Pathway
rn00625  Chloroalkane and chloroalkene degradation
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
Brite
Enzymatic reactions [BR:br08201]
 4. Lyase reactions
  4.1  Carbon-carbon lyases
   4.1.1  Carboxy-lyases
    4.1.1.-
     R06973  3-Oxopropanoate <=> Acetaldehyde + CO2
  4.2  Carbon-oxygen lyases
   4.2.1  Hydro-lyases
    4.2.1.155
     R06973  3-Oxopropanoate <=> Acetaldehyde + CO2
Orthology
K14422  malonate semialdehyde decarboxylase [EC:4.1.1.-]
Other DBs
RHEA: 45163
LinkDB

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