KEGG   REACTION: R11383
Entry
R11383                      Reaction                               
Name
aurachin C:NADPH:oxygen oxidoreductase (4-hydroxy-2-methyl-3-oxo-4-farnesyl-3,4-dihydroquinoline-1-oxide-forming)
Definition
Aurachin C + NADPH + H+ + Oxygen <=> 4-Hydroxy-2-methyl-3-oxo-4-[(2E,6E)-farnesyl]-3,4-dihydroquinoline 1-oxide + NADP+ + H2O
Equation
C21330 + C00005 + C00080 + C00007 <=> C21141 + C00006 + C00001
Comment
two-step reaction (see R11385+R11386)
Reaction class
RC03422  C21141_C21330
Enzyme
1.14.13.222
Pathway
rn00998  Biosynthesis of various antibiotics
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00848  Aurachin biosynthesis, anthranilate => aurachin A
Orthology
K21272  aurachin C monooxygenase/isomerase [EC:1.14.13.222]
Other DBs
RHEA: 49007
LinkDB

KEGG   REACTION: R11385
Entry
R11385                      Reaction                               
Name
aurachin C:NADPH:oxygen oxidoreductase (aurachin-C-epoxide-forming)
Definition
Aurachin C + NADPH + H+ + Oxygen <=> Aurachin C epoxide + NADP+ + H2O
Equation
C21330 + C00005 + C00080 + C00007 <=> C21331 + C00006 + C00001
Comment
first step of two-step reaction (see R11383, R11385+R11386)
Reaction class
RC03423  C21330_C21331
Enzyme
1.14.13.222
Other DBs
RHEA: 49011
LinkDB

KEGG   REACTION: R11386
Entry
R11386                      Reaction                               
Name
aurachin-C-epoxide mutase
Definition
Aurachin C epoxide <=> 4-Hydroxy-2-methyl-3-oxo-4-[(2E,6E)-farnesyl]-3,4-dihydroquinoline 1-oxide
Equation
C21331 <=> C21141
Comment
second step of two-step reaction (see R11382, R11384+R11386)
second step of two-step reaction (see R11383, R11385+R11386)
Reaction class
RC03424  C21141_C21331
Enzyme
1.14.13.222
LinkDB

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