KEGG   REACTION: R11442
Entry
R11442                      Reaction                               
Definition
(E)-4-Hydroxyphenylacetaldehyde oxime <=> (Z)-4-Hydroxyphenylacetaldehyde oxime
Equation
Comment
first step of three-step reaction (see R05728, R11442+R04306+R02708)
Reaction class
RC01159  C04350_C04353
Enzyme
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.37
     R11442  (E)-4-Hydroxyphenylacetaldehyde oxime <=> (Z)-4-Hydroxyphenylacetaldehyde oxime
Orthology
K13029  4-hydroxyphenylacetaldehyde oxime monooxygenase [EC:1.14.14.37]
Reference
1  [PMID:9484480]
  Authors
Bak S, Kahn RA, Nielsen HL, Moller BL, Halkier BA
  Title
Cloning of three A-type cytochromes P450, CYP71E1, CYP98, and CYP99 from Sorghum bicolor (L.) Moench by a PCR approach and identification by expression in Escherichia coli of CYP71E1 as a multifunctional cytochrome P450 in the biosynthesis of the cyanogenic glucoside dhurrin.
  Journal
Plant Mol Biol 36:393-405 (1998)
DOI:10.1023/A:1005915507497
Other DBs
RHEA: 50727
LinkDB

KEGG   REACTION: R04306
Entry
R04306                      Reaction                               
Definition
(Z)-4-Hydroxyphenylacetaldehyde oxime <=> 4-Hydroxyphenylacetonitrile + H2O
Equation
Comment
second step of three-step reaction (see R05728, R11442+R04306+R02708)
subsequently R02708
Reaction class
RC01076  C03766_C04353
Enzyme
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.37
     R04306  (Z)-4-Hydroxyphenylacetaldehyde oxime <=> 4-Hydroxyphenylacetonitrile + H2O
Orthology
K13029  4-hydroxyphenylacetaldehyde oxime monooxygenase [EC:1.14.14.37]
Reference
1  [PMID:9484480]
  Authors
Bak S, Kahn RA, Nielsen HL, Moller BL, Halkier BA
  Title
Cloning of three A-type cytochromes P450, CYP71E1, CYP98, and CYP99 from Sorghum bicolor (L.) Moench by a PCR approach and identification by expression in Escherichia coli of CYP71E1 as a multifunctional cytochrome P450 in the biosynthesis of the cyanogenic glucoside dhurrin.
  Journal
Plant Mol Biol 36:393-405 (1998)
DOI:10.1023/A:1005915507497
Other DBs
RHEA: 50731
LinkDB

KEGG   REACTION: R02708
Entry
R02708                      Reaction                               
Name
4-hydroxyphenylacetonitrile,[reduced NADPH-hemoprotein reductase]:oxygen oxidoreductase
Definition
4-Hydroxyphenylacetonitrile + Oxygen + [Reduced NADPH---hemoprotein reductase] <=> (S)-4-Hydroxymandelonitrile + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
Comment
last step of three-step reaction (see R05728, R11442+R04306+R02708)
following after R04306
Reaction class
RC02540  C03742_C03766
Enzyme
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.37
     R02708  4-Hydroxyphenylacetonitrile + Oxygen + [Reduced NADPH---hemoprotein reductase] <=> (S)-4-Hydroxymandelonitrile + [Oxidized NADPH---hemoprotein reductase] + H2O
Orthology
K13029  4-hydroxyphenylacetaldehyde oxime monooxygenase [EC:1.14.14.37]
Reference
1  [PMID:9484480]
  Authors
Bak S, Kahn RA, Nielsen HL, Moller BL, Halkier BA
  Title
Cloning of three A-type cytochromes P450, CYP71E1, CYP98, and CYP99 from Sorghum bicolor (L.) Moench by a PCR approach and identification by expression in Escherichia coli of CYP71E1 as a multifunctional cytochrome P450 in the biosynthesis of the cyanogenic glucoside dhurrin.
  Journal
Plant Mol Biol 36:393-405 (1998)
DOI:10.1023/A:1005915507497
Other DBs
RHEA: 50735
LinkDB

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