KEGG   REACTION: R11597
Entry
R11597                      Reaction                               
Name
(E)-2-methylbutanal oxime,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase
Definition
(E)-2-Methylbutanal oxime + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> (2R)-2-Hydroxy-2-methylbutanenitrile + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Equation
C19491 + C03024 + C00007 <=> C18796 + C03161 + 2 C00001
Comment
three-step reaction (see R10030+R11639+R11640)
Reaction class
RC03031  C18796_C19491
Enzyme
1.14.14.41
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.41
     R11597  (E)-2-Methylbutanal oxime + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> (2R)-2-Hydroxy-2-methylbutanenitrile + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Other DBs
RHEA: 28425
LinkDB

KEGG   REACTION: R10030
Entry
R10030                      Reaction                               
Definition
(E)-2-Methylbutanal oxime <=> (Z)-2-Methylbutanal oxime
Equation
C19491 <=> C20312
Comment
spontaneous
the first step of three-step reaction (see R11597, R10030+R11639+R11640)
Reaction class
RC03010  C19491_C20312
Enzyme
1.14.14.41
Pathway
rn00460  Cyanoamino acid metabolism
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.41
     R10030  (E)-2-Methylbutanal oxime <=> (Z)-2-Methylbutanal oxime
Orthology
K16265  (E)-2-methylbutanal oxime monooxygenase [EC:1.14.14.41]
Other DBs
RHEA: 51943
LinkDB

KEGG   REACTION: R11639
Entry
R11639                      Reaction                               
Definition
(Z)-2-Methylbutanal oxime <=> 2-Methylbutanenitrile + H2O
Equation
C20312 <=> C21525 + C00001
Comment
the second step of three-step reaction (see R11597, R10030+R11639+R11640)
Reaction class
RC03480  C20312_C21525
Enzyme
1.14.14.41
Pathway
rn00460  Cyanoamino acid metabolism
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.41
     R11639  (Z)-2-Methylbutanal oxime <=> 2-Methylbutanenitrile + H2O
Orthology
K16265  (E)-2-methylbutanal oxime monooxygenase [EC:1.14.14.41]
LinkDB

KEGG   REACTION: R11640
Entry
R11640                      Reaction                               
Definition
2-Methylbutanenitrile + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> (2R)-2-Hydroxy-2-methylbutanenitrile + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
C21525 + C03024 + C00007 <=> C18796 + C03161 + C00001
Comment
the last step of three-step reaction (see R11597, R10030+R11639+R11640)
Reaction class
RC03481  C18796_C21525
Enzyme
1.14.14.41
Pathway
rn00460  Cyanoamino acid metabolism
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.41
     R11640  2-Methylbutanenitrile + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> (2R)-2-Hydroxy-2-methylbutanenitrile + [Oxidized NADPH---hemoprotein reductase] + H2O
Orthology
K16265  (E)-2-methylbutanal oxime monooxygenase [EC:1.14.14.41]
Other DBs
RHEA: 51951
LinkDB

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