KEGG   REACTION: R11734
Entry
R11734                      Reaction                               
Name
(E)-indol-3-ylacetaldoxime,[reduced NADPH---hemoprotein reductase],glutathione:oxygen oxidoreductase (oxime-hydroxylating)
Definition
Indole-3-acetaldehyde oxime + [Reduced NADPH---hemoprotein reductase] + Glutathione + Oxygen <=> S-[(E)-N-Hydroxy(indol-3-yl)acetimidoyl]-L-glutathione + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Equation
Comment
two-step reaction (see R11735+R11736)
Reaction class
RC03482  C02937_C21620
Enzyme
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.45
     R11734  Indole-3-acetaldehyde oxime + [Reduced NADPH---hemoprotein reductase] + Glutathione + Oxygen <=> S-[(E)-N-Hydroxy(indol-3-yl)acetimidoyl]-L-glutathione + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Other DBs
RHEA: 52183
LinkDB

KEGG   REACTION: R11735
Entry
R11735                      Reaction                               
Definition
Indole-3-acetaldehyde oxime + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Indole-3-acetaldoxime N-oxide + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
Comment
the first step of two-step reaction (see R11734, R11735+R11736)
Reaction class
RC02452  C02937_C17204
Enzyme
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.45
     R11735  Indole-3-acetaldehyde oxime + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Indole-3-acetaldoxime N-oxide + [Oxidized NADPH---hemoprotein reductase] + H2O
Other DBs
RHEA: 52187
LinkDB

KEGG   REACTION: R11736
Entry
R11736                      Reaction                               
Definition
Indole-3-acetaldoxime N-oxide + Glutathione <=> S-[(E)-N-Hydroxy(indol-3-yl)acetimidoyl]-L-glutathione + H2O
Equation
Comment
spontaneous
the second step of two-step reaction (see R11734, R11735+R11736)
Reaction class
RC02367  C17204_C21620
Enzyme
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.45
     R11736  Indole-3-acetaldoxime N-oxide + Glutathione <=> S-[(E)-N-Hydroxy(indol-3-yl)acetimidoyl]-L-glutathione + H2O
Other DBs
RHEA: 52191
LinkDB

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