KEGG   REACTION: R11737
Entry
R11737                      Reaction                               
Name
(E)-phenylacetaldehyde oxime,[reduced NADPH---hemoprotein reductase],glutathione:oxygen oxidoreductase (oxime-hydroxylating)
Definition
(E)-Phenylacetaldoxime + [Reduced NADPH---hemoprotein reductase] + Glutathione + Oxygen <=> S-[(Z)-N-Hydroxy(phenyl)acetimidoyl]-L-glutathione + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Equation
Comment
two-step reaction (see R11738+R11739)
Reaction class
RC02210  C19714_C21622
Enzyme
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.45
     R11737  (E)-Phenylacetaldoxime + [Reduced NADPH---hemoprotein reductase] + Glutathione + Oxygen <=> S-[(Z)-N-Hydroxy(phenyl)acetimidoyl]-L-glutathione + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Other DBs
RHEA: 52195
LinkDB

KEGG   REACTION: R11738
Entry
R11738                      Reaction                               
Definition
(E)-Phenylacetaldoxime + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> 1-aci-Nitro-2-phenylethane + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
Comment
the first step of two-step reaction (see R11737, R11738+R11739)
Reaction class
RC02452  C19714_C21623
Enzyme
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.45
     R11738  (E)-Phenylacetaldoxime + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> 1-aci-Nitro-2-phenylethane + [Oxidized NADPH---hemoprotein reductase] + H2O
Other DBs
RHEA: 52199
LinkDB

KEGG   REACTION: R11739
Entry
R11739                      Reaction                               
Definition
1-aci-Nitro-2-phenylethane + Glutathione <=> S-[(Z)-N-Hydroxy(phenyl)acetimidoyl]-L-glutathione + H2O
Equation
Comment
spontaneous
the second step of two-step reaction (see R11737, R11738+R11739)
Reaction class
RC02367  C21622_C21623
Enzyme
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.45
     R11739  1-aci-Nitro-2-phenylethane + Glutathione <=> S-[(Z)-N-Hydroxy(phenyl)acetimidoyl]-L-glutathione + H2O
Other DBs
RHEA: 52203
LinkDB

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