KEGG   REACTION: R12007
Entry
R12007                      Reaction                               
Name
cucurbitadienol,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (11-oxocucurbitadienol forming)
Definition
Cucurbitadienol + 2 [Reduced NADPH---hemoprotein reductase] + 2 Oxygen <=> 11-Oxocucurbitadienol + 2 [Oxidized NADPH---hemoprotein reductase] + 3 H2O
Equation
C19819 + 2 C03024 + 2 C00007 <=> C21841 + 2 C03161 + 3 C00001
Comment
two-step reaction (see R12008+R12009)
Reaction class
RC03494  C19819_C21841
Enzyme
1.14.14.71
Pathway
rn00996  Biosynthesis of various alkaloids
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.71
     R12007  Cucurbitadienol + 2 [Reduced NADPH---hemoprotein reductase] + 2 Oxygen <=> 11-Oxocucurbitadienol + 2 [Oxidized NADPH---hemoprotein reductase] + 3 H2O
Orthology
K25060  cucurbitadienol 11-hydroxylase / 11-oxocucurbitadienol 20-hydroxylase [EC:1.14.14.71 1.14.14.-]
Other DBs
RHEA: 55511
LinkDB

KEGG   REACTION: R12008
Entry
R12008                      Reaction                               
Definition
Cucurbitadienol + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> 11-Hydroxycucurbitadienol + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
C19819 + C03024 + C00007 <=> C21842 + C03161 + C00001
Comment
the first step of two-step reaction (see R12007, R12008+R12009)
Reaction class
RC01218  C19819_C21842
Enzyme
1.14.14.71
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.71
     R12008  Cucurbitadienol + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> 11-Hydroxycucurbitadienol + [Oxidized NADPH---hemoprotein reductase] + H2O
Other DBs
RHEA: 55515
LinkDB

KEGG   REACTION: R12009
Entry
R12009                      Reaction                               
Definition
11-Hydroxycucurbitadienol + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> 11-Oxocucurbitadienol + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Equation
C21842 + C03024 + C00007 <=> C21841 + C03161 + 2 C00001
Comment
the second step of two-step reaction (see R12007, R12008+R12009)
Reaction class
RC00127  C21841_C21842
Enzyme
1.14.14.71
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.71
     R12009  11-Hydroxycucurbitadienol + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> 11-Oxocucurbitadienol + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Other DBs
RHEA: 55519
LinkDB

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