KEGG   REACTION: R12030
Entry
R12030                      Reaction                               
Name
1H-pyrrole-2-carbonyl-[peptidyl-carrier protein]:FADH2 oxidoreductase (brominating)
Definition
Pyrrole-2-carbonyl-[pcp] + 3 FADH2 + 3 Bromide + 3 Oxygen <=> 3,4,5-Tribromo-1H-pyrrole-2-carbonyl-[peptidyl-carrier protein] + 3 FAD + 6 H2O
Equation
C12483 + 3 C01352 + 3 C01324 + 3 C00007 <=> C21864 + 3 C00016 + 6 C00001
Comment
three-step reaction (see R12027+R12028+R12029)
Enzyme
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.19  With oxidation of a pair of donors resulting in the reduction of O2 to two molecules of water
    1.14.19.57
     R12030  Pyrrole-2-carbonyl-[pcp] + 3 FADH2 + 3 Bromide + 3 Oxygen <=> 3,4,5-Tribromo-1H-pyrrole-2-carbonyl-[peptidyl-carrier protein] + 3 FAD + 6 H2O
Other DBs
RHEA: 56471
LinkDB

KEGG   REACTION: R12027
Entry
R12027                      Reaction                               
Definition
Pyrrole-2-carbonyl-[pcp] + FADH2 + Bromide + Oxygen <=> 5-Bromo-1H-pyrrole-2-carbonyl-[peptidyl-carrier protein] + FAD + 2 H2O
Equation
Comment
the first step of three-step reaction (see R12030, R12027+R12028+R12029)
Enzyme
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.19  With oxidation of a pair of donors resulting in the reduction of O2 to two molecules of water
    1.14.19.57
     R12027  Pyrrole-2-carbonyl-[pcp] + FADH2 + Bromide + Oxygen <=> 5-Bromo-1H-pyrrole-2-carbonyl-[peptidyl-carrier protein] + FAD + 2 H2O
Other DBs
RHEA: 56475
LinkDB

KEGG   REACTION: R12028
Entry
R12028                      Reaction                               
Definition
5-Bromo-1H-pyrrole-2-carbonyl-[peptidyl-carrier protein] + FADH2 + Bromide + Oxygen <=> 4,5-Dibromo-1H-pyrrole-2-carbonyl-[peptidyl-carrier protein] + FAD + 2 H2O
Equation
Comment
the second step of three-step reaction (see R12030, R12027+R12028+R12029)
Reaction class
RC00949  C21862_C21863
Enzyme
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.19  With oxidation of a pair of donors resulting in the reduction of O2 to two molecules of water
    1.14.19.57
     R12028  5-Bromo-1H-pyrrole-2-carbonyl-[peptidyl-carrier protein] + FADH2 + Bromide + Oxygen <=> 4,5-Dibromo-1H-pyrrole-2-carbonyl-[peptidyl-carrier protein] + FAD + 2 H2O
Other DBs
RHEA: 56479
LinkDB

KEGG   REACTION: R12029
Entry
R12029                      Reaction                               
Definition
4,5-Dibromo-1H-pyrrole-2-carbonyl-[peptidyl-carrier protein] + FADH2 + Bromide + Oxygen <=> 3,4,5-Tribromo-1H-pyrrole-2-carbonyl-[peptidyl-carrier protein] + FAD + 2 H2O
Equation
Comment
the last step of three-step reaction (see R12030, R12027+R12028+R12029)
Reaction class
RC01363  C21863_C21864
Enzyme
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.19  With oxidation of a pair of donors resulting in the reduction of O2 to two molecules of water
    1.14.19.57
     R12029  4,5-Dibromo-1H-pyrrole-2-carbonyl-[peptidyl-carrier protein] + FADH2 + Bromide + Oxygen <=> 3,4,5-Tribromo-1H-pyrrole-2-carbonyl-[peptidyl-carrier protein] + FAD + 2 H2O
Other DBs
RHEA: 56483
LinkDB

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