KEGG   REACTION: R13408
Entry
R13408                      Reaction                               
Name
5-methoxy-2-methyl-3-(all-trans-polyprenyl)benzoquinone,NADH:oxygen oxidoreductase (5-hydroxylating)
Definition
2-Polyprenyl-3-methyl-6-methoxy-1,4-benzoquinone + NADH + Oxygen <=> 2-Polyprenyl-3-methyl-5-hydroxy-6-methoxy-1,4-benzoquinone + NAD+ + H2O
Equation
C17561 + C00004 + C00007 <=> C17562 + C00003 + C00001
Comment
general reaction
Reaction class
RC01254  C17561_C17562
Enzyme
1.14.13.253
Pathway
rn00130  Ubiquinone and other terpenoid-quinone biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01240  Biosynthesis of cofactors
Module
M00128  Ubiquinone biosynthesis, eukaryotes, 4-hydroxybenzoate + polyprenyl-PP => ubiquinone
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.13  With NADH or NADPH as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.13.253
     R13408  2-Polyprenyl-3-methyl-6-methoxy-1,4-benzoquinone + NADH + Oxygen <=> 2-Polyprenyl-3-methyl-5-hydroxy-6-methoxy-1,4-benzoquinone + NAD+ + H2O
Orthology
K28034  3-demethoxyubiquinone 3-hydroxylase (NADH) [EC:1.14.13.253]
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