KEGG   REACTION: R13418
Entry
R13418                      Reaction                               
Name
3-oxoacyl-[acyl-carrier protein]:glycerone phosphate 3-oxoacyltransferase
Definition
3-Oxoacyl-[acyl-carrier protein] + Glycerone phosphate <=> (4-Alkanoyl-5-oxo-2,5-dihydrofuran-3-yl)methyl phosphate + H2O + Acyl-carrier protein
Equation
Comment
two-step reaction (see R12289+R13419)
Enzyme
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.3  Acyltransferases
   2.3.1  Transferring groups other than aminoacyl groups
    2.3.1.277
     R13418  3-Oxoacyl-[acyl-carrier protein] + Glycerone phosphate <=> (4-Alkanoyl-5-oxo-2,5-dihydrofuran-3-yl)methyl phosphate + H2O + Acyl-carrier protein
Orthology
K22463  2-oxo-3-(phosphooxy)propyl 3-oxoalkanoate synthase [EC:2.3.1.277]
Reference
1  [PMID:33146163]
  Authors
Zhou S, Malet NR, Song L, Corre C, Challis GL.
  Title
MmfL catalyses formation of a phosphorylated butenolide intermediate in methylenomycin furan biosynthesis.
  Journal
Chem Commun (Camb) 56:14443-14446 (2020)
DOI:10.1039/d0cc05658h
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