KEGG   REACTION: R13505
Entry
R13505                      Reaction                               
Name
3-(4-hydroxyphenyl)pyruvate:3-(4-hydroxyphenyl)pyruvate ligase (atromentin-forming)
Definition
2 ATP + 2 3-(4-Hydroxyphenyl)pyruvate <=> 2 AMP + 2 Diphosphate + Atromentin
Equation
2 C00002 + 2 C01179 <=> 2 C00020 + 2 C00013 + C23042
Comment
two-step reaction (see  R13506+R13507)
Enzyme
6.4.1.10
Pathway
rn00350  Tyrosine metabolism
Brite
Enzymatic reactions [BR:br08201]
 6. Ligase reactions
  6.4  Forming carbon-carbon bonds
   6.4.1  Ligases that form carbon-carbon bonds (only sub-subclass identified to date)
    6.4.1.10
     R13505  2 ATP + 2 3-(4-Hydroxyphenyl)pyruvate <=> 2 AMP + 2 Diphosphate + Atromentin
Orthology
K28347  atromentin synthase [EC:6.4.1.10]
LinkDB

KEGG   REACTION: R13506
Entry
R13506                      Reaction                               
Definition
ATP + 3-(4-Hydroxyphenyl)pyruvate + Peptidyl-carrier protein <=> AMP + Diphosphate + 3-(4-Hydroxyphenyl)pyruvoyl-[pcp]
Equation
C00002 + C01179 + C21097 <=> C00020 + C00013 + C23041
Comment
the first step of the two-step reaction (see R13505, R13506+R13507)
Enzyme
6.4.1.10
Brite
Enzymatic reactions [BR:br08201]
 6. Ligase reactions
  6.4  Forming carbon-carbon bonds
   6.4.1  Ligases that form carbon-carbon bonds (only sub-subclass identified to date)
    6.4.1.10
     R13506  ATP + 3-(4-Hydroxyphenyl)pyruvate + Peptidyl-carrier protein <=> AMP + Diphosphate + 3-(4-Hydroxyphenyl)pyruvoyl-[pcp]
LinkDB

KEGG   REACTION: R13507
Entry
R13507                      Reaction                               
Definition
ATP + 3-(4-Hydroxyphenyl)pyruvate + 3-(4-Hydroxyphenyl)pyruvoyl-[pcp] <=> AMP + Diphosphate + Atromentin + Peptidyl-carrier protein
Equation
C00002 + C01179 + C23041 <=> C00020 + C00013 + C23042 + C21097
Comment
the second step of two-step reaction (see R13505, R13506+R13507)
Enzyme
6.4.1.10
Brite
Enzymatic reactions [BR:br08201]
 6. Ligase reactions
  6.4  Forming carbon-carbon bonds
   6.4.1  Ligases that form carbon-carbon bonds (only sub-subclass identified to date)
    6.4.1.10
     R13507  ATP + 3-(4-Hydroxyphenyl)pyruvate + 3-(4-Hydroxyphenyl)pyruvoyl-[pcp] <=> AMP + Diphosphate + Atromentin + Peptidyl-carrier protein
Orthology
K28347  atromentin synthase [EC:6.4.1.10]
LinkDB

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