KEGG   REACTION: R13526
Entry
R13526                      Reaction                               
Name
(indol-3-yl)pyruvate:(indol-3-yl)pyruvate ligase (didemethylasterriquinone D-forming)
Definition
2 ATP + 2 Indolepyruvate <=> 2 AMP + 2 Diphosphate + Didemethylasterriquinone D
Equation
2 C00002 + 2 C00331 <=> 2 C00020 + 2 C00013 + C23064
Comment
two-step reaction (see R13527+R13528)
Enzyme
6.4.1.12
Pathway
rn00380  Tryptophan metabolism
Brite
Enzymatic reactions [BR:br08201]
 6. Ligase reactions
  6.4  Forming carbon-carbon bonds
   6.4.1  Ligases that form carbon-carbon bonds (only sub-subclass identified to date)
    6.4.1.12
     R13526  2 ATP + 2 Indolepyruvate <=> 2 AMP + 2 Diphosphate + Didemethylasterriquinone D
Orthology
K28345  didemethylasterriquinone D synthase [EC:6.4.1.12]
LinkDB

KEGG   REACTION: R13527
Entry
R13527                      Reaction                               
Definition
ATP + Indolepyruvate + Peptidyl-carrier protein <=> ATP + Diphosphate + (Indol-3-yl)pyruvoyl-[peptidyl-carrier protein]
Equation
C00002 + C00331 + C21097 <=> C00002 + C00013 + C23063
Comment
the first step of two-step reaction (see R13526, R13527+R13528)
Enzyme
6.4.1.12
Brite
Enzymatic reactions [BR:br08201]
 6. Ligase reactions
  6.4  Forming carbon-carbon bonds
   6.4.1  Ligases that form carbon-carbon bonds (only sub-subclass identified to date)
    6.4.1.12
     R13527  ATP + Indolepyruvate + Peptidyl-carrier protein <=> ATP + Diphosphate + (Indol-3-yl)pyruvoyl-[peptidyl-carrier protein]
Orthology
K28345  didemethylasterriquinone D synthase [EC:6.4.1.12]
LinkDB

KEGG   REACTION: R13528
Entry
R13528                      Reaction                               
Definition
ATP + Indolepyruvate + (Indol-3-yl)pyruvoyl-[peptidyl-carrier protein] <=> ATP + Diphosphate + Didemethylasterriquinone D + Peptidyl-carrier protein
Equation
C00002 + C00331 + C23063 <=> C00002 + C00013 + C23064 + C21097
Comment
the second step of two-step reaction (see R13526, R13527+R13528)
Enzyme
6.4.1.12
Brite
Enzymatic reactions [BR:br08201]
 6. Ligase reactions
  6.4  Forming carbon-carbon bonds
   6.4.1  Ligases that form carbon-carbon bonds (only sub-subclass identified to date)
    6.4.1.12
     R13528  ATP + Indolepyruvate + (Indol-3-yl)pyruvoyl-[peptidyl-carrier protein] <=> ATP + Diphosphate + Didemethylasterriquinone D + Peptidyl-carrier protein
Orthology
K28345  didemethylasterriquinone D synthase [EC:6.4.1.12]
LinkDB

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