KEGG   REACTION: R13550
Entry
R13550                      Reaction                               
Name
5,20-epoxytaxa-11-en-4alpha-yl acetate,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (9alpha-hydroxylating)
Definition
5,20-Epoxytaxa-11-en-4alpha-yl acetate + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> 5,20-Epoxy-9alpha-hydroxytaxa-11-en-4alpha-yl acetate + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
C23033 + C03024 + C00007 <=> C23070 + C03161 + C00001
Reaction class
RC01218  C23033_C23070
Enzyme
1.14.14.185
Pathway
rn00904  Diterpenoid biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.185
     R13550  5,20-Epoxytaxa-11-en-4alpha-yl acetate + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> 5,20-Epoxy-9alpha-hydroxytaxa-11-en-4alpha-yl acetate + [Oxidized NADPH---hemoprotein reductase] + H2O
Orthology
K27503  taxane 9alpha-hydroxylase [EC:1.14.14.185]
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