KEGG   COMPOUND: C15973
Entry
C15973                      Compound                               

Name
Enzyme N6-(dihydrolipoyl)lysine;
Dihydrolipoamide-E;
[E2 protein]-N6-[(R)-dihydrolipoyl]-L-lysine;
[Lipoyl-carrier protein E2]-N6-[(R)-dihydrolipoyl]-L-lysine
Formula
C8H16NOS2R
Structure
Comment
Generic compound in reaction hierarchy
The reduced lipoyllysine residue in EC 2.3.1.12, dihydrolipoyllysine-residue acetyltransferase ( EC 2.3.1.61, dihydrolipoyllysine-residue succinyltransferase or EC 2.3.1.168, dihydrolipoyllysine-residue (2-methylpropanoyl)transferase ).
Reaction
Pathway
map00010  Glycolysis / Gluconeogenesis
map00020  Citrate cycle (TCA cycle)
map00280  Valine, leucine and isoleucine degradation
map00620  Pyruvate metabolism
map00640  Propanoate metabolism
map00785  Lipoic acid metabolism
map01100  Metabolic pathways
map01240  Biosynthesis of cofactors
Module
M00009  Citrate cycle (TCA cycle, Krebs cycle)
M00011  Citrate cycle, second carbon oxidation, 2-oxoglutarate => oxaloacetate
M00036  Leucine degradation, leucine => acetoacetate + acetyl-CoA
M00307  Pyruvate oxidation, pyruvate => acetyl-CoA
M00881  Lipoic acid biosynthesis, plants and bacteria, octanoyl-ACP => dihydrolipoyl-E2/H
M00883  Lipoic acid biosynthesis, animals and bacteria, octanoyl-ACP => dihydrolipoyl-H => dihydrolipoyl-E2
M00884  Lipoic acid biosynthesis, octanoyl-CoA => dihydrolipoyl-E2
Enzyme
1.8.1.4         1.11.1.28       2.3.1.12        2.3.1.61        
2.3.1.168       2.8.1.8
Other DBs
PubChem: 47205286
ChEBI: 80219
LinkDB
KCF data

ATOM        13
            1   C1c C    15.4683  -15.8087
            2   C1b C    16.6705  -16.5090
            3   C1b C    14.2660  -16.5090
            4   S1a S    15.4683  -14.4255
            5   C1b C    17.8728  -15.8087
            6   C1b C    13.0639  -15.8087
            7   C1b C    19.0808  -16.5090
            8   S1a S    13.0639  -14.4255
            9   C1b C    20.2771  -15.8087
            10  C5a C    21.4794  -16.5090
            11  O5a O    21.4794  -17.8921
            12  N1b N    22.8334  -15.8379
            13  R   R    24.2335  -15.8379
BOND        12
            1     1   2 1 #Down
            2     1   3 1
            3     1   4 1
            4     2   5 1
            5     3   6 1
            6     5   7 1
            7     6   8 1
            8     7   9 1
            9     9  10 1
            10   10  11 2
            11   10  12 1
            12   12  13 1

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