REACTION: R03278
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Entry
R03278 Reaction
Name
2-hydroxycyclohexan-1-one:NAD+ oxidoreductase
Definition
2-Hydroxycyclohexan-1-one + NAD+ <=> Cyclohexane-1,2-dione + NADH + H+
Equation
C01147
+
C00003
<=>
C06105
+
C00004
+
C00080
Comment
trans-cyclohexane-1,2-diol:NAD+ 1-oxidoreductase
Reaction class
RC00001
C00003_C00004
RC00897
C01147_C06105
Enzyme
1.1.1.174
Pathway
rn00930
Caprolactam degradation
rn01120
Microbial metabolism in diverse environments
Brite
Enzymatic reactions [BR:
br08201
]
1. Oxidoreductase reactions
1.1 Acting on the CH-OH group of donors
1.1.1 With NAD+ or NADP+ as acceptor
1.1.1.174
R03278 2-Hydroxycyclohexan-1-one + NAD+ <=> Cyclohexane-1,2-dione + NADH + H+
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RCLASS: RC00897
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Entry
RC00897 RClass
Definition
C1y-C5x:*-*:C1x+C5x+O1a-C1x+C5x+O5x
Reactant pair
C01147_C06105
C06620_C11922
C06620_C11928
Related class
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Reaction
R03278
R05526
R11051
Enzyme
1.1.1.174
1.1.1.384
1.1.1.-
Pathway
rn00523
Polyketide sugar unit biosynthesis
rn00930
Caprolactam degradation
rn01100
Metabolic pathways
rn01110
Biosynthesis of secondary metabolites
rn01120
Microbial metabolism in diverse environments
rn01250
Biosynthesis of nucleotide sugars
RModule
RM038
Deoxygenation (dehydration and reduction) in deoxysugar biosynthesis
Orthology
K13315
NDP-hexose C3-ketoreductase / dTDP-4-oxo-2-deoxy-alpha-D-pentos-2-ene 2,3-reductase [EC:1.1.1.-]
K13327
dTDP-3,4-didehydro-2,6-dideoxy-alpha-D-glucose 3-reductase [EC:
1.1.1.384
]
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