KEGG   REACTION: R03278
Entry
R03278                      Reaction                               
Name
2-hydroxycyclohexan-1-one:NAD+ oxidoreductase
Definition
2-Hydroxycyclohexan-1-one + NAD+ <=> Cyclohexane-1,2-dione + NADH + H+
Equation
C01147 + C00003 <=> C06105 + C00004 + C00080
Comment
trans-cyclohexane-1,2-diol:NAD+ 1-oxidoreductase
Reaction class
RC00001  C00003_C00004
RC00897  C01147_C06105
Enzyme
1.1.1.174
Pathway
rn00930  Caprolactam degradation
rn01120  Microbial metabolism in diverse environments
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.1  Acting on the CH-OH group of donors
   1.1.1  With NAD+ or NADP+ as acceptor
    1.1.1.174
     R03278  2-Hydroxycyclohexan-1-one + NAD+ <=> Cyclohexane-1,2-dione + NADH + H+
LinkDB

KEGG   RCLASS: RC00897
Entry
RC00897                     RClass                                 
Definition
C1y-C5x:*-*:C1x+C5x+O1a-C1x+C5x+O5x
Reactant pair
C01147_C06105    C06620_C11922    C06620_C11928
Related class
Reaction
R03278 R05526 R11051
Enzyme
1.1.1.174       1.1.1.384       1.1.1.-
Pathway
rn00523  Polyketide sugar unit biosynthesis
rn00930  Caprolactam degradation
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01120  Microbial metabolism in diverse environments
rn01250  Biosynthesis of nucleotide sugars
RModule
RM038  Deoxygenation (dehydration and reduction) in deoxysugar biosynthesis
Orthology
K13315  NDP-hexose C3-ketoreductase / dTDP-4-oxo-2-deoxy-alpha-D-pentos-2-ene 2,3-reductase [EC:1.1.1.-]
K13327  dTDP-3,4-didehydro-2,6-dideoxy-alpha-D-glucose 3-reductase [EC:1.1.1.384]

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