KEGG   REACTION: R05359
Entry
R05359                      Reaction                               
Name
2-hydroxy-6-oxo-6-(4'-chlorophenyl)-hexa-2,4-dienoate benzoylhydrolase
Definition
2-Hydroxy-6-oxo-6-(4'-chlorophenyl)-hexa-2,4-dienoate + H2O <=> 4-Chlorobenzoate + 2-Hydroxy-2,4-pentadienoate
Equation
C06587 + C00001 <=> C02370 + C00596
Comment
BphD
Reaction class
RC00753  C00596_C06587
RC00757  C02370_C06587
Enzyme
3.7.1.8
Pathway
rn00621  Dioxin degradation
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
Module
M00543  Biphenyl degradation, biphenyl => 2-oxopent-4-enoate + benzoate
Brite
Enzymatic reactions [BR:br08201]
 3. Hydrolase reactions
  3.7  Acting on carbon-carbon bonds
   3.7.1  In ketonic substances
    3.7.1.8
     R05359  2-Hydroxy-6-oxo-6-(4'-chlorophenyl)-hexa-2,4-dienoate + H2O <=> 4-Chlorobenzoate + 2-Hydroxy-2,4-pentadienoate
Orthology
K10222  2,6-dioxo-6-phenylhexa-3-enoate hydrolase [EC:3.7.1.8]
LinkDB

KEGG   RCLASS: RC00753
Entry
RC00753                     RClass                                 
Definition
C2a-C2b:*-C5a:C2b-C2b
Reactant pair
C00596_C01273    C00596_C04479    C00596_C06210
C00596_C06582    C00596_C06587    C00596_C07087
C00596_C07123    C00596_C07731    C00596_C08062
C00596_C12624    C00596_C16264    C06645_C11353
Related class
Reaction
R02603 R02606 R05138 R05359 R05360 R05362 R05363 R05364
R05365 R05366 R06789 R07802
Enzyme
3.7.1.8         3.7.1.9         3.7.1.13        3.7.1.14        
3.7.1.25        3.7.1.-
Pathway
rn00360  Phenylalanine metabolism
rn00621  Dioxin degradation
rn00622  Xylene degradation
rn00642  Ethylbenzene degradation
rn00643  Styrene degradation
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
RModule
RM009  Meta-cleavage of dihydroxylated aromatic ring
RM010  Dihydroxylation and meta-cleavage of aromatic ring, type 1
RM011  Dihydroxylation and meta-cleavage of aromatic ring, type 1b
Orthology
K05714  2-hydroxy-6-oxonona-2,4-dienedioate hydrolase [EC:3.7.1.14]
K10216  2-hydroxymuconate-semialdehyde hydrolase [EC:3.7.1.9]
K10222  2,6-dioxo-6-phenylhexa-3-enoate hydrolase [EC:3.7.1.8]
K10623  HOMODA hydrolase [EC:3.7.1.-]
K10702  2-hydroxy-6-oxohepta-2,4-dienoate hydrolase [EC:3.7.1.25]
K14604  2-hydroxy-6-oxo-6-(2'-carboxyphenyl)-hexa-2,4-dienoate hydrolase [EC:3.7.1.-]
K15756  2-hydroxy-6-oxo-6-(2'-aminophenyl)hexa-2,4-dienoate hydrolase [EC:3.7.1.13]
K18092  2-hydroxy-6-oxo-octa-2,4-dienoate hydrolase [EC:3.7.1.-]
K22677  2,6-dioxo-6-phenylhexa-3-enoate/TCOA hydrolase [EC:3.7.1.-]
K22717  2-hydroxy-6-oxo-6-(2-hydroxyphenoxy)-hexa-2,4-dienoate hydrolase [EC:3.7.1.-]

KEGG   RCLASS: RC00757
Entry
RC00757                     RClass                                 
Definition
C5a-C6a:C2b+*-*+O6a:C8y+O5a-C8y+O6a
Reactant pair
C00108_C08062    C00180_C01273    C00805_C07731
C01606_C16264    C02370_C06587    C18338_C18349
Related class
Reaction
R02606 R05359 R05360 R05365 R07802 R09277
Enzyme
3.7.1.8         3.7.1.13        3.7.1.-
Pathway
rn00621  Dioxin degradation
rn00624  Polycyclic aromatic hydrocarbon degradation
rn00627  Aminobenzoate degradation
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
Orthology
K10222  2,6-dioxo-6-phenylhexa-3-enoate hydrolase [EC:3.7.1.8]
K14604  2-hydroxy-6-oxo-6-(2'-carboxyphenyl)-hexa-2,4-dienoate hydrolase [EC:3.7.1.-]
K15062  OH-DDVA meta-cleavage compound hydrolase
K15756  2-hydroxy-6-oxo-6-(2'-aminophenyl)hexa-2,4-dienoate hydrolase [EC:3.7.1.13]
K22717  2-hydroxy-6-oxo-6-(2-hydroxyphenoxy)-hexa-2,4-dienoate hydrolase [EC:3.7.1.-]

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