KEGG   REACTION: R06982
Entry
R06982                      Reaction                               
Name
S-(hydroxymethyl)glutathione formaldehyde-lyase (glutathione-forming);
S-(hydroxymethyl)glutathione synthase
Definition
Glutathione + Formaldehyde <=> S-(Hydroxymethyl)glutathione
Equation
C00051 + C00067 <=> C14180
Comment
spontaneous
This reaction is accelerated by enzyme ec 4.4.1.22.
Reaction class
RC00069  C00051_C14180
RC01707  C00067_C14180
Enzyme
4.4.1.22
Pathway
rn00680  Methane metabolism
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
rn01200  Carbon metabolism
Brite
Enzymatic reactions [BR:br08201]
 4. Lyase reactions
  4.4  Carbon-sulfur lyases
   4.4.1  Carbon-sulfur lyases (only sub-subclass identified to date)
    4.4.1.22
     R06982  Glutathione + Formaldehyde <=> S-(Hydroxymethyl)glutathione
Orthology
K03396  S-(hydroxymethyl)glutathione synthase [EC:4.4.1.22]
Other DBs
RHEA: 22491
LinkDB

KEGG   REACTION: R06983
Entry
R06983                      Reaction                               
Name
S-(hydroxymethyl)glutathione dehydrogenase
Definition
S-(Hydroxymethyl)glutathione + NAD+ <=> S-Formylglutathione + NADH + H+
Equation
C14180 + C00003 <=> C01031 + C00004 + C00080
Reaction class
RC00001  C00003_C00004
RC01715  C01031_C14180
Enzyme
1.1.1.284
Pathway
rn00680  Methane metabolism
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
rn01200  Carbon metabolism
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.1  Acting on the CH-OH group of donors
   1.1.1  With NAD+ or NADP+ as acceptor
    1.1.1.284
     R06983  S-(Hydroxymethyl)glutathione + NAD+ <=> S-Formylglutathione + NADH + H+
Orthology
K00121  S-(hydroxymethyl)glutathione dehydrogenase / alcohol dehydrogenase [EC:1.1.1.284 1.1.1.1]
Other DBs
RHEA: 19988
LinkDB

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