KEGG   REACTION: R08645
Entry
R08645                      Reaction                               
Name
2-(3'-methylthio)heptylmalate hydroxymutase
Definition
2-(7'-Methylthio)heptylmalic acid <=> 3-(7'-Methylthio)heptylmalic acid
Equation
C17230 <=> C17231
Comment
two-step reaction (similar to R10170, R03968+R04001)
Reaction class
RC00497  C17230_C17231
Enzyme
4.2.1.170
Pathway
rn00966  Glucosinolate biosynthesis
rn01210  2-Oxocarboxylic acid metabolism
Brite
Enzymatic reactions [BR:br08201]
 4. Lyase reactions
  4.2  Carbon-oxygen lyases
   4.2.1  Hydro-lyases
    4.2.1.170
     R08645  2-(7'-Methylthio)heptylmalic acid <=> 3-(7'-Methylthio)heptylmalic acid
Orthology
K01703  3-isopropylmalate/(R)-2-methylmalate dehydratase large subunit [EC:4.2.1.33 4.2.1.35]
K21359  3-isopropylmalate/methylthioalkylmalate dehydratase small subunit [EC:4.2.1.33 4.2.1.170]
LinkDB

KEGG   RCLASS: RC00497
Entry
RC00497                     RClass                                 
Definition
C1b-C1c:*-O1a:C1d+C6a-C1c+C6a
C1d-C1c:O1a-*:C1b+C1b+C6a-C1b+C1c+C6a
O1a-O1a:C1d+*-*+C1c:*-*
Reactant pair
C00158_C00311    C01251_C05662    C16583_C16597
C16598_C16600    C17210_C17212    C17214_C17215
C17218_C17219    C17222_C17223    C17226_C17227
C17230_C17231    C17947_C21372    C20653_C20654
Related class
Reaction
R01324 R08620 R08624 R08628 R08634 R08641 R08645 R09720
R10391 R10394 R10501 R11408
Enzyme
4.2.1.3         4.2.1.114       4.2.1.166       4.2.1.170       
4.2.1.-
Pathway
rn00400  Phenylalanine, tyrosine and tryptophan biosynthesis
rn00440  Phosphonate and phosphinate metabolism
rn00966  Glucosinolate biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01120  Microbial metabolism in diverse environments
rn01200  Carbon metabolism
rn01210  2-Oxocarboxylic acid metabolism
rn01230  Biosynthesis of amino acids
rn01240  Biosynthesis of cofactors
RModule
RM001  2-Oxocarboxylic acid chain extension by tricarboxylic acid pathway
Orthology
K01681  aconitate hydratase [EC:4.2.1.3]
K01682  aconitate hydratase 2 / 2-methylisocitrate dehydratase [EC:4.2.1.3 4.2.1.99]
K01703  3-isopropylmalate/(R)-2-methylmalate dehydratase large subunit [EC:4.2.1.33 4.2.1.35]
K16792  methanogen homoaconitase large subunit [EC:4.2.1.114]
K16793  methanogen homoaconitase small subunit [EC:4.2.1.114]
K17749  3-benzylmalate isomerase [EC:4.2.1.-]
K20930  phosphinomethylmalate isomerase [EC:4.2.1.166]
K21359  3-isopropylmalate/methylthioalkylmalate dehydratase small subunit [EC:4.2.1.33 4.2.1.170]
K27802  aconitate hydratase A / 2-methylisocitrate dehydratase [EC:4.2.1.3 4.2.1.99]

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