KEGG   REACTION: R08679
Entry
R08679                      Reaction                               
Name
amino acid:2-oxo-acid aminotransferase
Definition
Amino acid + 2-Oxo acid <=> Amino acid + 2-Oxo acid
Equation
C00045 + C00161 <=> C00045 + C00161
Comment
a part of chain-elongation cycle (see R08792)
general reaction (see R08618, R08622, R08626, R08630, R08638 and R08643)
Reaction class
RC00025  C00045_C00161
Enzyme
2.6.1.-
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.6  Transferring nitrogenous groups
   2.6.1  Transaminases
    2.6.1.-
     R08679  Amino acid + 2-Oxo acid <=> Amino acid + 2-Oxo acid
LinkDB

KEGG   REACTION: R08680
Entry
R08680                      Reaction                               
Name
acetyl-CoA:2-oxo-acid C-acetyltransferase (thioester-hydrolysing, carboxymethyl-forming)
Definition
2-Oxo acid + Acetyl-CoA + H2O <=> 2-Alkylmalic acid + CoA
Equation
C00161 + C00024 + C00001 <=> C17263 + C00010
Comment
a part of chain-elongation cycle (see R08792)
general reaction (see R08619, R08623, R08627, R08631, R08640 and R08644)
Reaction class
RC00004  C00010_C00024
RC02340  C00161_C17263
Enzyme
2.3.3.-
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.3  Acyltransferases
   2.3.3  Acyl groups converted into alkyl groups on transfer
    2.3.3.-
     R08680  2-Oxo acid + Acetyl-CoA + H2O <=> 2-Alkylmalic acid + CoA
LinkDB

KEGG   REACTION: R08681
Entry
R08681                      Reaction                               
Name
2-alkylmalate hydroxymutase
Definition
2-Alkylmalic acid <=> 3-Alkylmalic acid
Equation
C17263 <=> C17264
Comment
a part of chain-elongation cycle (see R08792)
possibly two-step reaction (similar to ec 4.2.1.33, R03968+R04001)
general reaction (see R08620, R08624, R08628, R08634, R08641 and R08645)
Reaction class
RC02341  C17263_C17264
Enzyme
5.4.4.-
Brite
Enzymatic reactions [BR:br08201]
 5. Isomerase reactions
  5.4  Intramolecular transferases
   5.4.4  Transferring hydroxy groups
    5.4.4.-
     R08681  2-Alkylmalic acid <=> 3-Alkylmalic acid
LinkDB

KEGG   REACTION: R08682
Entry
R08682                      Reaction                               
Name
3-alkylmalate oxidoreductase (decarboxylating)
Definition
3-Alkylmalic acid <=> Aliphatic oxo acid + CO2
Equation
C17264 <=> C17265 + C00011
Comment
a part of chain-elongation cycle (see R08792)
incomplete reaction (unidentified acceptor, possibly NAD+[CPD:C00003], similar to ec 1.1.1.85, R04426+R01652)
general reaction (see R08621, R08625, R08629, R08636, R08642 and R08646)
Reaction class
RC02342  C17264_C17265
Enzyme
1.1.1.-
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.1  Acting on the CH-OH group of donors
   1.1.1  With NAD+ or NADP+ as acceptor
    1.1.1.-
     R08682  3-Alkylmalic acid <=> Aliphatic oxo acid + CO2
LinkDB

KEGG   REACTION: R08683
Entry
R08683                      Reaction                               
Name
amino acid:2-oxo-acid aminotransferase
Definition
Aliphatic oxo acid + Amino acid <=> Homoamino acid + 2-Oxo acid
Equation
C17265 + C00045 <=> C17266 + C00161
Comment
a part of chain-elongation cycle (see R08792)
general reaction (see R08622, R08626, R08630, R08638, R08643 and R08647)
Reaction class
RC00006  C17265_C17266
RC00025  C00045_C00161
Enzyme
2.6.1.-
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.6  Transferring nitrogenous groups
   2.6.1  Transaminases
    2.6.1.-
     R08683  Aliphatic oxo acid + Amino acid <=> Homoamino acid + 2-Oxo acid
LinkDB

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