KEGG   REACTION: R10246
Entry
R10246                      Reaction                               
Name
L-tyrosine 4-methylphenol-lyase (2-iminoacetate-forming)
Definition
L-Tyrosine + S-Adenosyl-L-methionine + Reduced acceptor <=> Iminoglycine + 4-Cresol + 5'-Deoxyadenosine + L-Methionine + Acceptor
Equation
C00082 + C00019 + C00030 <=> C15809 + C01468 + C05198 + C00073 + C00028
Comment
radical SAM
Reaction class
RC00021  C00019_C00073
RC01434  C00082_C01468
RC03095  C00082_C15809
Enzyme
4.1.99.19
Pathway
rn00730  Thiamine metabolism
rn01100  Metabolic pathways
rn01240  Biosynthesis of cofactors
Module
M00127  Thiamine biosynthesis, prokaryotes, AIR (+ DXP/tyrosine) => TMP/TPP
Orthology
K03150  2-iminoacetate synthase [EC:4.1.99.19]
Other DBs
RHEA: 26364
LinkDB

KEGG   RCLASS: RC03095
Entry
RC03095                     RClass                                 
Definition
C1c-C2b:C1b-*:C6a+N1a-C6a+N2a
N1a-N2a:*-*:C1c-C2b
Reactant pair
C00082_C15809
Related class
Reaction
R10246 R12161
Enzyme
2.5.1.147       4.1.99.19
Pathway
rn00730  Thiamine metabolism
rn01100  Metabolic pathways
rn01240  Biosynthesis of cofactors
Orthology
K03150  2-iminoacetate synthase [EC:4.1.99.19]
K11779  FO synthase [EC:2.5.1.147 4.3.1.32]
K11781  5-amino-6-(D-ribitylamino)uracil---L-tyrosine 4-hydroxyphenyl transferase [EC:2.5.1.147]

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