KEGG   REACTION: R11960
Entry
R11960                      Reaction                               
Name
L-glutamate:FMN aminotransferase (oxidizing, decarboxylating)
Definition
L-Glutamate + FMN + Oxygen + H2O + 3 Acceptor <=> 2-Oxoglutarate + 8-Amino-8-demethylriboflavin 5'-phosphate + CO2 + 3 Reduced acceptor
Equation
C00025 + C00061 + C00007 + C00001 + 3 C00028 <=> C00026 + C21805 + C00011 + 3 C00030
Comment
three-step reaction (see R11961+R11962+R11963)
Reaction class
RC00006  C00025_C00026
RC03519  C00061_C21805
Enzyme
2.6.1.114
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.6  Transferring nitrogenous groups
   2.6.1  Transaminases
    2.6.1.114
     R11960  L-Glutamate + FMN + Oxygen + H2O + 3 Acceptor <=> 2-Oxoglutarate + 8-Amino-8-demethylriboflavin 5'-phosphate + CO2 + 3 Reduced acceptor
Orthology
K22598  8-demethyl-8-aminoriboflavin-5'-phosphate synthase [EC:2.6.1.114]
Other DBs
RHEA: 54995
LinkDB

KEGG   REACTION: R11961
Entry
R11961                      Reaction                               
Definition
FMN + Oxygen <=> 8-Demethyl-8-formylriboflavin 5'-phosphate + H2O
Equation
C00061 + C00007 <=> C21803 + C00001
Comment
a part of three-step reaction (see R11960, R11961+R11962+R11963)
Reaction class
RC00769  C00061_C21803
Enzyme
2.6.1.114
Pathway
rn00998  Biosynthesis of various antibiotics
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00890  Roseoflavin biosynthesis, FMN => roseoflavin
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.6  Transferring nitrogenous groups
   2.6.1  Transaminases
    2.6.1.114
     R11961  FMN + Oxygen <=> 8-Demethyl-8-formylriboflavin 5'-phosphate + H2O
Orthology
K22598  8-demethyl-8-aminoriboflavin-5'-phosphate synthase [EC:2.6.1.114]
LinkDB

KEGG   REACTION: R11962
Entry
R11962                      Reaction                               
Definition
8-Demethyl-8-formylriboflavin 5'-phosphate + H2O + Acceptor <=> 8-Carboxy-8-demethylriboflavin 5'-phosphate + Reduced acceptor
Equation
C21803 + C00001 + C00028 <=> C21804 + C00030
Comment
a part of three-step reaction (see R11960, R11961+R11962+R11963)
Reaction class
RC00075  C21803_C21804
Enzyme
2.6.1.114
Pathway
rn00998  Biosynthesis of various antibiotics
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00890  Roseoflavin biosynthesis, FMN => roseoflavin
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.6  Transferring nitrogenous groups
   2.6.1  Transaminases
    2.6.1.114
     R11962  8-Demethyl-8-formylriboflavin 5'-phosphate + H2O + Acceptor <=> 8-Carboxy-8-demethylriboflavin 5'-phosphate + Reduced acceptor
Orthology
K22598  8-demethyl-8-aminoriboflavin-5'-phosphate synthase [EC:2.6.1.114]
LinkDB

KEGG   REACTION: R11963
Entry
R11963                      Reaction                               
Definition
L-Glutamate + 8-Carboxy-8-demethylriboflavin 5'-phosphate + H2O + 2 Acceptor <=> 2-Oxoglutarate + 8-Amino-8-demethylriboflavin 5'-phosphate + CO2 + 2 Reduced acceptor
Equation
C00025 + C21804 + C00001 + 2 C00028 <=> C00026 + C21805 + C00011 + 2 C00030
Comment
a part of three-step reaction (see R11960, R11961+R11962+R11963)
Reaction class
RC00006  C00025_C00026
RC03520  C21804_C21805
Enzyme
2.6.1.114
Pathway
rn00998  Biosynthesis of various antibiotics
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00890  Roseoflavin biosynthesis, FMN => roseoflavin
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.6  Transferring nitrogenous groups
   2.6.1  Transaminases
    2.6.1.114
     R11963  L-Glutamate + 8-Carboxy-8-demethylriboflavin 5'-phosphate + H2O + 2 Acceptor <=> 2-Oxoglutarate + 8-Amino-8-demethylriboflavin 5'-phosphate + CO2 + 2 Reduced acceptor
Orthology
K22598  8-demethyl-8-aminoriboflavin-5'-phosphate synthase [EC:2.6.1.114]
LinkDB

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