KEGG   REACTION: R13546
Entry
R13546                      Reaction                               
Definition
4-(1-Methyl-2-pyrrolidinyl)-3-oxobutanoate + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Ecgonone + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Equation
C22421 + C03024 + C00007 <=> C23036 + C03161 + 2 C00001
Enzyme
1.14.14.194
Pathway
rn00960  Tropane, piperidine and pyridine alkaloid biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.194
     R13546  4-(1-Methyl-2-pyrrolidinyl)-3-oxobutanoate + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Ecgonone + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Orthology
K25581  ecgonone synthase [EC:1.14.14.194]
K28354  ecgonone synthase [EC:1.14.14.194]
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