KEGG Orthology (KO) [BR:ko00001]
09100 Metabolism
09110 Biosynthesis of other secondary metabolites
00997 Biosynthesis of various other secondary metabolites
K23668 FMQD; fumiquinazoline A oxidase
Complexity generation in fungal peptidyl alkaloid biosynthesis: oxidation of fumiquinazoline A to the heptacyclic hemiaminal fumiquinazoline C by the flavoenzyme Af12070 from Aspergillus fumigatus.
Co-ordination between BrlA regulation and secretion of the oxidoreductase FmqD directs selective accumulation of fumiquinazoline C to conidial tissues in Aspergillus fumigatus.
Enzymatic reactions [BR:br08201]
1. Oxidoreductase reactions
1.5 Acting on the CH-NH group of donors
1.5.3 With oxygen as acceptor
1.5.3.-
R12420 Fumiquinazoline A + Oxygen <=> Fumiquinazoline C + Hydrogen peroxide