PATHWAY: tcc00999 Help 
Entry  
 
Name  
Biosynthesis of various plant secondary metabolites
 
  Including  
Crocin biosynthesis, Ginsenoside biosynthesis, Saponin adjuvant biosynthesis, Cannabidiol biosynthesis, Mugineic acid biosynthesis, Pentagalloylglucose biosynthesis, Benzoxazinoid biosynthesis, Gramine biosynthesis, Coumarin biosynthesis, Furanocoumarin biosynthesis, Hordatine biosynthesis, Podophyllotoxin biosynthesis - Theobroma cacao (cacao)
 
Class  
Metabolism; Biosynthesis of other secondary metabolites 
BRITE hierarchy 
 
Pathway map  
tcc00999   Biosynthesis of various plant secondary metabolites 
 
Organism  
Theobroma cacao (cacao) [GN:
tcc ]
 
Gene  
 
Compound  
C00019   S-Adenosyl-L-methionine 
C00353   Geranylgeranyl diphosphate 
C00448   trans,trans-Farnesyl diphosphate 
C01158   1-O-Galloyl-beta-D-glucose 
C01198   3-(2-Hydroxyphenyl)propanoate 
C01772   trans-2-Hydroxycinnamate 
C03506   Indoleglycerol phosphate 
C05158   trans-beta-D-Glucosyl-2-hydroxycinnamate 
C05839   cis-beta-D-Glucosyl-2-hydroxycinnamate 
C10557   Dihydroanhydropodorhizol 
C15486   3''-Deamino-3''-oxonicotianamine 
C15501   3-Epihydroxymugineic acid 
C15502   3-Epihydroxy-2'-deoxymugineic acid 
C17513   trans-Crocetin (beta-D-glucosyl) (beta-D-gentibiosyl) ester 
C19731   (3S)-3-Hydroxycyclocitral 
C19867   beta-D-Glucosyl crocetin 
C19868   Bis(beta-D-glucosyl) crocetin 
C19869   beta-D-Gentiobiosyl crocetin 
C20413   3,5,7-Trioxododecanoyl-CoA 
C20417   2,4-Dihydroxy-6-pentylbenzoate 
C20456   (+)-Secoisolariciresinol 
C21602   (1H-Indol-3-yl)-N-methylmethanamine 
C21903   Delta9-Tetrahydrocannabinolate 
C22070   2,4-Dihydroxycinnamoyl-CoA 
C22156   6',7'-Dihydroxybergamottin 
C22452   6,7,8-Trihydroxycoumarin 
C22652   Quillaic acid 3-O-beta-D-glucuronide 
C22653   Quillaic acid 3-O-beta-D-galactosyl-1,2-beta-D-glucuronide 
C22654   Quillaic acid 3-O-beta-D-xylosyl-1,3-(beta-D-galactosyl-1,2)-beta-D-glucuronide 
C22655   Quillaic acid 3-O-alpha-L-rhamnosyl-1,3-(beta-D-galactosyl-1,2)-beta-D-glucuronide 
C22656   Quillaic acid 3-O-beta-D-xylosyl-1,3-(beta-D-galactosyl-1,2)-beta-D-glucuronide-28-O-beta-D-fucoside 
C22657   Quillaic acid 3-O-alpha-L-rhamnosyl-1,3-(beta-D-galactosyl-1,2)-beta-D-glucuronide-28-O-beta-D-fucoside 
C22658   Quillaic acid 3-O-beta-D-xylosyl-1,3-(beta-D-galactosyl-1,2)-beta-D-glucuronide-28-O-alpha-L-rhamnosyl-1,2-beta-D-fucoside 
C22659   Quillaic acid 3-O-alpha-L-rhamnosyl-1,3-(beta-D-galactosyl-1,2)-beta-D-glucuronide-28-O-alpha-L-rhamnosyl-1,2-beta-D-fucoside 
C22660   Quillaic acid 3-O-beta-D-xylosyl-1,3-(beta-D-galactosyl-1,2)-beta-D-glucuronide-28-O-beta-D-xylosyl-1,4-alpha-L-rhamnosyl-1,2-beta-D-fucoside 
C22661   Quillaic acid 3-O-alpha-L-rhamnosyl-1,3-(beta-D-galactosyl-1,2)-beta-D-glucuronide-28-O-beta-D-xylosyl-1,4-alpha-L-rhamnosyl-1,2-beta-D-fucoside 
C22662   Quillaic acid 3-O-beta-D-xylosyl-1,3-(beta-D-galactosyl-1,2)-beta-D-glucuronide-28-O-beta-D-xylosyl-1,3-beta-D-xylosyl-1,4-alpha-L-rhamnosyl-1,2-beta-D-fucoside 
C22663   Quillaic acid 3-O-alpha-L-rhamnosyl-1,3-(beta-D-galactosyl-1,2)-beta-D-glucuronide-28-O-beta-D-xylosyl-1,3-beta-D-xylosyl-1,4-alpha-L-rhamnosyl-1,2-beta-D-fucoside 
C22664   Quillaic acid 3-O-beta-D-xylosyl-1,3-(beta-D-galactosyl-1,2)-beta-D-glucuronide-28-O-beta-D-apiosyl-1,3-beta-D-xylosyl-1,4-alpha-L-rhamnosyl-1,2-beta-D-fucoside 
C22665   Quillaic acid 3-O-alpha-L-rhamnosyl-1,3-(beta-D-galactosyl-1,2)-beta-D-glucuronide-28-O-beta-D-apiosyl-1,3-beta-D-xylosyl-1,4-alpha-L-rhamnosyl-1,2-beta-D-fucoside 
C22666   Quillaic acid 3-O-beta-D-xylosyl-1,3-(beta-D-galactosyl-1,2)-beta-D-glucuronide 28-O-beta-D-apiosyl-1,3-beta-D-xylosyl-1,4-(beta-D-glucosyl-1,3)-alpha-L-rhamnosyl-1,2-(alpha-L-rhamnosyl-1,3)-4-O-acetyl-beta-D-fucoside 
 
Reference  
 
  Authors  
Nagatoshi M, Terasaka K, Owaki M, Sota M, Inukai T, Nagatsu A, Mizukami H
 
  Title  
UGT75L6 and UGT94E5 mediate sequential glucosylation of crocetin to crocin in Gardenia jasminoides.
 
  Journal  
 
Reference  
 
  Authors  
Taura F, Sirikantaramas S, Shoyama Y, Yoshikai K, Shoyama Y, Morimoto S
 
  Title  
Cannabidiolic-acid synthase, the chemotype-determining enzyme in the fiber-type Cannabis sativa.
 
  Journal  
 
Reference  
 
  Authors  
Higuchi K, Suzuki K, Nakanishi H, Yamaguchi H, Nishizawa NK, Mori S
 
  Title  
Cloning of nicotianamine synthase genes, novel genes involved in the biosynthesis of phytosiderophores.
 
  Journal  
 
Reference  
 
  Authors  
Ma JF, Shinada T, Matsuda C, Nomoto K
 
  Title  
Biosynthesis of phytosiderophores, mugineic acids, associated with methionine cycling.
 
  Journal  
 
Reference  
 
  Authors  
Tahara K, Nishiguchi M, Funke E, Miyazawa SI, Miyama T, Milkowski C
 
  Title  
Dehydroquinate dehydratase/shikimate dehydrogenases involved in gallate biosynthesis of the aluminum-tolerant tree species Eucalyptus camaldulensis.
 
  Journal  
 
Reference  
 
  Authors  
Dugrand-Judek A, Olry A, Hehn A, Costantino G, Ollitrault P, Froelicher Y, Bourgaud F.
 
  Title  
The Distribution of Coumarins and Furanocoumarins in Citrus Species Closely Matches Citrus Phylogeny and Reflects the Organization of Biosynthetic Pathways.
 
  Journal  
 
Reference  
 
  Authors  
Hehmann M, Lukacin R, Ekiert H, Matern U
 
  Title  
Furanocoumarin biosynthesis in Ammi majus L. Cloning of bergaptol O-methyltransferase.
 
  Journal  
 
Reference  
 
  Authors  
Lau W, Sattely ES
 
  Title  
Six enzymes from mayapple that complete the biosynthetic pathway to the etoposide aglycone.
 
  Journal  
 
Reference  
 
  Authors  
Reed J, Orme A, El-Demerdash A, Owen C, Martin LBB, Misra RC, Kikuchi S, Rejzek M, Martin AC, Harkess A, Leebens-Mack J, Louveau T, Stephenson MJ, Osbourn A.
 
  Title  
Elucidation of the pathway for biosynthesis of saponin adjuvants from the soapbark tree.
 
  Journal  
 
Related pathway  
tcc00270   Cysteine and methionine metabolism 
tcc00400   Phenylalanine, tyrosine and tryptophan biosynthesis 
tcc00900   Terpenoid backbone biosynthesis 
 
KO pathway