KEGG   REACTION: R12341
Entry
R12341                      Reaction                               
Name
S-adenosyl-L-methionine:D-histidine N-[(3S)-3-amino-3-carboxypropyl]-transferase
Definition
S-Adenosyl-L-methionine + D-Histidine <=> (2S)-2-Amino-4-{[(1R)-1-carboxy-2-(1H-imidazol-4-yl)ethyl]amino}butanoate + 5'-Methylthioadenosine
Equation
C00019 + C06419 <=> C22025 + C00170
Reaction class
RC00215  C06419_C22025
Enzyme
2.5.1.152
Pathway
rn00470  D-Amino acid metabolism
rn01100  Metabolic pathways
Module
M00949  Staphylopine biosynthesis, L-histidine => staphylopine
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.5  Transferring alkyl or aryl groups, other than methyl groups
   2.5.1  Transferring alkyl or aryl groups, other than methyl groups (only sub-subclass identified to date)
    2.5.1.152
     R12341  S-Adenosyl-L-methionine + D-Histidine <=> (2S)-2-Amino-4-{[(1R)-1-carboxy-2-(1H-imidazol-4-yl)ethyl]amino}butanoate + 5'-Methylthioadenosine
Orthology
K23120  histidine 2-aminobutanoyltransferase [EC:2.5.1.152 2.5.1.-]
LinkDB

KEGG   RCLASS: RC00215
Entry
RC00215                     RClass                                 
Definition
N1a-N1b:*-C1b:C1c-C1c
Reactant pair
C00025_C00449    C00025_C21559    C00062_C06655
C06419_C22025
Related class
Reaction
R02313 R02315 R05465 R09495 R11705 R12341
Enzyme
1.5.1.9         1.5.1.10        1.5.3.18        2.5.1.66        
2.5.1.140       2.5.1.152
Pathway
rn00331  Clavulanic acid biosynthesis
rn00470  D-Amino acid metabolism
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Orthology
K00293  saccharopine dehydrogenase (NADP+, L-glutamate forming) [EC:1.5.1.10]
K12673  N2-(2-carboxyethyl)arginine synthase [EC:2.5.1.66]
K14157  alpha-aminoadipic semialdehyde synthase [EC:1.5.1.8 1.5.1.9]
K21949  N-(2-amino-2-carboxyethyl)-L-glutamate synthase [EC:2.5.1.140]
K23120  histidine 2-aminobutanoyltransferase [EC:2.5.1.152 2.5.1.-]
K24034  spermidine synthase / saccharopine dehydrogenase (NADP+, L-glutamate-forming) [EC:2.5.1.16 1.5.1.10]

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