KEGG   REACTION: R13551
Entry
R13551                      Reaction                               
Name
5,20-epoxy-9alpha-hydroxytaxa-11-en-4alpha-yl acetate:oxygen 9-oxidoreductase
Definition
5,20-Epoxy-9alpha-hydroxytaxa-11-en-4alpha-yl acetate + 2-Oxoglutarate + Oxygen <=> 5,20-Epoxy-9-oxotaxa-11-en-4alpha-yl acetate + Succinate + CO2 + H2O
Equation
C23070 + C00026 + C00007 <=> C23071 + C00042 + C00011 + C00001
Reaction class
RC00127  C23070_C23071
Enzyme
1.14.20.16
Pathway
rn00904  Diterpenoid biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.20  With 2-oxoglutarate as one donor, and the other dehydrogenated
    1.14.20.16
     R13551  5,20-Epoxy-9alpha-hydroxytaxa-11-en-4alpha-yl acetate + 2-Oxoglutarate + Oxygen <=> 5,20-Epoxy-9-oxotaxa-11-en-4alpha-yl acetate + Succinate + CO2 + H2O
LinkDB

KEGG   RCLASS: RC00127
Entry
RC00127                     RClass                                 
Definition
C1y-C5x:*-*:C1x+C1z+O1a-C1x+C1z+O5x
Reactant pair
C00280_C00535    C00468_C00951    C00468_C02537
C00523_C03852    C00674_C03917    C00695_C01292
C00808_C01765    C00809_C01766    C00848_C03092
C01227_C04295    C01292_C04661    C02943_C03930
C05284_C18075    C05291_C05296    C07276_C11937
C18015_C18016    C18019_C18020    C19082_C19083
C20320_C20322    C20320_C20323    C21841_C21842
C23070_C23071
Related class
Reaction
R01836 R01838 R02347 R02349 R02352 R02353 R02793 R02944
R02945 R02994 R03406 R03407 R03495 R04099 R04760 R06399
R08916 R08917 R08919 R08945 R08980 R09388 R12009 R13039
R13094 R13095 R13219 R13220 R13221 R13551
Enzyme
1.1.1.51        1.1.1.62        1.1.1.64        1.1.1.148       
1.1.1.176       1.1.1.198       1.1.1.227       1.1.1.230       
1.1.1.238       1.1.1.239       1.1.1.241       1.1.1.295       
1.1.1.297       1.1.1.-         1.14.14.71      1.14.20.16
Pathway
rn00140  Steroid hormone biosynthesis
rn00902  Monoterpenoid biosynthesis
rn00903  Limonene degradation
rn00904  Diterpenoid biosynthesis
rn00907  Pinene, camphor and geraniol degradation
rn00984  Steroid degradation
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01120  Microbial metabolism in diverse environments
Orthology
K00044  17beta-estradiol 17-dehydrogenase [EC:1.1.1.62]
K04119  aldo-keto reductase family 1 member C3 [EC:1.1.1.51 1.1.1.188 1.1.1.213 1.1.1.357]
K05296  3(or 17)beta-hydroxysteroid dehydrogenase [EC:1.1.1.51]
K10207  testosterone 17beta-dehydrogenase (NADP+) [EC:1.1.1.64]
K10251  17beta-estradiol 17-dehydrogenase / very-long-chain 3-oxoacyl-CoA reductase [EC:1.1.1.62 1.1.1.330]
K13070  momilactone-A synthase [EC:1.1.1.295]
K13368  17beta-estradiol 17-dehydrogenase / 3alpha(17beta)-hydroxysteroid dehydrogenase (NAD+) [EC:1.1.1.62 1.1.1.239]
K13369  17beta-estradiol 17-dehydrogenase / all-trans-retinol dehydrogenase (NAD+) / 3alpha(17beta)-hydroxysteroid dehydrogenase (NAD+) [EC:1.1.1.62 1.1.1.105 1.1.1.239]
K13370  17beta-estradiol 17-dehydrogenase / 3alpha(17beta)-hydroxysteroid dehydrogenase (NAD+) / 3-oxoacyl-[acyl-carrier protein] reductase alpha subunit [EC:1.1.1.62 1.1.1.239]
K13373  17beta-estradiol 17-dehydrogenase / 3beta-hydroxysteroid 3-dehydrogenase [EC:1.1.1.62 1.1.1.270]
K25779  hydroxysteroid 17beta dehydrogenase 11 [EC:1.1.1.-]

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