KEGG   COMPOUND: C00219
Entry
C00219                      Compound                               
Name
Arachidonate;
Arachidonic acid;
(5Z,8Z,11Z,14Z)-Icosatetraenoic acid;
cis-5,8,11,14-Eicosatetraenoic acid;
5Z,8Z,11Z,14Z-Eicosatetraenoic acid;
(5Z,8Z,11Z,14Z)-Icosa-5,8,11,14-tetraenoic acid
Formula
C20H32O2
Exact mass
304.2402
Mol weight
304.47
Structure
Reaction
R01317 R01590 R01593 R01594 R01595 R01596 R01598 R01599
R07038 R07041 R07046 R07047 R07048 R07049 R07050 R07051
R07052 R07053 R07054 R08183 R08527 R09536
Pathway
map00590  Arachidonic acid metabolism
map00591  Linoleic acid metabolism
map01040  Biosynthesis of unsaturated fatty acids
map01100  Metabolic pathways
map04216  Ferroptosis
map04217  Necroptosis
map04270  Vascular smooth muscle contraction
map04611  Platelet activation
map04664  Fc epsilon RI signaling pathway
map04666  Fc gamma R-mediated phagocytosis
map04723  Retrograde endocannabinoid signaling
map04726  Serotonergic synapse
map04730  Long-term depression
map04745  Phototransduction - fly
map04750  Inflammatory mediator regulation of TRP channels
map04912  GnRH signaling pathway
map04913  Ovarian steroidogenesis
map04921  Oxytocin signaling pathway
map04923  Regulation of lipolysis in adipocytes
map04925  Aldosterone synthesis and secretion
map05140  Leishmaniasis
map05146  Amoebiasis
map07034  Eicosanoids
Network
nt06525  Ferroptosis
Enzyme
1.13.11.31      1.13.11.33      1.13.11.34      1.13.11.40      
1.13.11.-       1.14.14.1       1.14.14.80      1.14.14.-       
1.14.99.1       3.1.1.4         3.1.2.2         3.5.1.99        
6.2.1.15
Brite
Compounds with biological roles [BR:br08001]
 Lipids
  Fatty acids
   Unsaturated fatty acids
    C00219  Arachidonic acid (20:4;5,8,11,14)
Lipids [BR:br08002]
 FA  Fatty acyls
  FA01 Fatty Acids and Conjugates
   FA0103 Unsaturated fatty acids
    Polyunsaturated fatty acids
     C00219  (5Z,8Z,11Z,14Z)-Icosa-5,8,11,14-tetraenoic acid
Other DBs
CAS: 506-32-1
PubChem: 3519
ChEBI: 15843
LIPIDMAPS: LMFA01030001
KNApSAcK: C00000388
PDB-CCD: ACD[PDBj]
NIKKAJI: J12.228I
LinkDB
KCF data

ATOM        22
            1   C2b C    22.3315  -17.1355
            2   C2b C    23.7282  -17.1355
            3   C1b C    21.1172  -17.8373
            4   C1b C    24.9423  -17.8373
            5   C2b C    19.9101  -17.1355
            6   C2b C    26.1566  -17.1355
            7   C2b C    18.5065  -17.1355
            8   C2b C    27.5533  -17.1355
            9   C1b C    17.3062  -17.8373
            10  C1b C    28.7673  -17.8373
            11  C1b C    16.0850  -17.1355
            12  C2b C    29.9745  -17.1355
            13  C1b C    14.8707  -17.8373
            14  C2b C    31.3783  -17.1355
            15  C6a C    13.6636  -17.1355
            16  C1b C    32.5924  -17.8373
            17  O6a O    12.4495  -17.8373
            18  O6a O    13.6636  -15.7386
            19  C1b C    33.7996  -17.1355
            20  C1b C    35.0139  -17.8373
            21  C1b C    36.2210  -17.1355
            22  C1a C    37.4353  -17.8373
BOND        21
            1     1   2 2
            2     1   3 1
            3     2   4 1
            4     3   5 1
            5     4   6 1
            6     5   7 2
            7     6   8 2
            8     7   9 1
            9     8  10 1
            10    9  11 1
            11   10  12 1
            12   11  13 1
            13   12  14 2
            14   13  15 1
            15   14  16 1
            16   15  17 1
            17   15  18 2
            18   16  19 1
            19   19  20 1
            20   20  21 1
            21   21  22 1

» Japanese version

KEGG   COMPOUND: C16527
Entry
C16527                      Compound                               
Name
Adrenic acid;
7,10,13,16-Docosatetraenoic acid;
(7Z,10Z,13Z,16Z)-Docosa-7,10,13,16-tetraenoic acid;
7Z,10Z,13Z,16Z-Docosatetraenoic acid
Formula
C22H36O2
Exact mass
332.2715
Mol weight
332.52
Structure
Reaction
R08191
Pathway
map01040  Biosynthesis of unsaturated fatty acids
map04216  Ferroptosis
Network
nt06525  Ferroptosis
Enzyme
3.1.2.-
Brite
Lipids [BR:br08002]
 FA  Fatty acyls
  FA01 Fatty Acids and Conjugates
   FA0103 Unsaturated fatty acids
    Polyunsaturated fatty acids
     C16527  (7Z,10Z,13Z,16Z)-Docosa-7,10,13,16-tetraenoic acid
  FA04 Docosanoids
   FA0400 Other Docosanoids
    C16527  (7Z,10Z,13Z,16Z)-Docosa-7,10,13,16-tetraenoic acid
Other DBs
CAS: 28874-58-0
PubChem: 51090856
ChEBI: 53487
LIPIDMAPS: LMFA01030178
NIKKAJI: J13.758H
LinkDB
KCF data

ATOM        24
            1   C1b C    13.9300  -21.9100
            2   C1b C    12.7400  -21.2100
            3   C1b C    11.4800  -21.9100
            4   C6a C    10.2200  -21.2100
            5   O6a O     9.0300  -21.9100
            6   O6a O    10.2200  -19.8100
            7   C1b C    15.1200  -21.2100
            8   C1b C    16.3800  -21.9100
            9   C2b C    17.5700  -21.2100
            10  C2b C    18.9700  -21.2100
            11  C1b C    20.2300  -21.8400
            12  C2b C    21.4200  -21.1400
            13  C2b C    22.8200  -21.1400
            14  C1b C    24.0100  -21.8400
            15  C2b C    25.2000  -21.1400
            16  C2b C    26.6000  -21.1400
            17  C1b C    27.8600  -21.7700
            18  C2b C    29.1200  -21.0700
            19  C2b C    30.5200  -21.0700
            20  C1b C    31.7800  -21.7700
            21  C1b C    32.9700  -21.0700
            22  C1b C    34.1600  -21.7700
            23  C1b C    35.4200  -21.0700
            24  C1a C    36.6100  -21.7700
BOND        23
            1     1   2 1
            2     2   3 1
            3     3   4 1
            4     4   5 1
            5     4   6 2
            6     1   7 1
            7     7   8 1
            8     9   8 1
            9     9  10 2
            10   10  11 1
            11   11  12 1
            12   12  13 2
            13   13  14 1
            14   15  14 1
            15   15  16 2
            16   16  17 1
            17   17  18 1
            18   18  19 2
            19   19  20 1
            20   20  21 1
            21   21  22 1
            22   22  23 1
            23   23  24 1

» Japanese version

KEGG   COMPOUND: C00010
Entry
C00010                      Compound                               
Name
CoA;
Coenzyme A;
CoA-SH
Formula
C21H36N7O16P3S
Exact mass
767.1152
Mol weight
767.54
Structure
Reaction
R00091 R00130 R00209 R00210 R00211 R00212 R00227 R00228
R00229 R00230 R00235 R00236 R00238 R00259 R00265 R00271
R00351 R00352 R00371 R00383 R00389 R00390 R00391 R00394
R00395 R00399 R00405 R00407 R00432 R00454 R00468 R00472
R00487 R00521 R00577 R00586 R00627 R00664 R00693 R00705
R00706 R00727 R00740 R00829 R00830 R00832 R00851 R00918
R00920 R00921 R00922 R00925 R00926 R00927 R00931 R00932
R00935 R00982 R00989 R00998 R01013 R01023 R01075 R01089
R01111 R01154 R01160 R01172 R01173 R01174 R01176 R01177
R01180 R01196 R01197 R01199 R01204 R01210 R01213 R01256
R01274 R01277 R01280 R01281 R01300 R01301 R01318 R01319
R01322 R01357 R01358 R01368 R01422 R01461 R01496 R01556
R01558 R01598 R01613 R01614 R01615 R01616 R01617 R01624
R01625 R01626 R01651 R01776 R01777 R01798 R01806 R01807
R01808 R01850 R01889 R01923 R01933 R01941 R01943 R01944
R01945 R01946 R01952 R01978 R01999 R02058 R02081 R02082
R02083 R02138 R02152 R02191 R02193 R02194 R02195 R02220
R02221 R02224 R02241 R02242 R02251 R02255 R02366 R02367
R02375 R02385 R02387 R02396 R02402 R02404 R02405 R02406
R02416 R02447 R02450 R02452 R02453 R02481 R02482 R02505
R02506 R02539 R02543 R02569 R02570 R02571 R02576 R02616
R02617 R02620 R02662 R02694 R02699 R02760 R02764 R02772
R02794 R02837 R02899 R02911 R02986 R03017 R03040 R03056
R03064 R03065 R03109 R03157 R03158 R03168 R03171 R03174
R03209 R03210 R03230 R03352 R03374 R03381 R03383 R03437
R03438 R03455 R03552 R03621 R03631 R03668 R03695 R03718
R03719 R03720 R03727 R03735 R03755 R03756 R03760 R03762
R03767 R03778 R03779 R03838 R03858 R03859 R03861 R03903
R03910 R03932 R03965 R03974 R03991 R03992 R03994 R04021
R04022 R04024 R04030 R04050 R04097 R04150 R04157 R04192
R04205 R04211 R04254 R04316 R04348 R04356 R04361 R04363
R04364 R04365 R04413 R04466 R04480 R04484 R04507 R04546
R04580 R04618 R04709 R04723 R04742 R04747 R04776 R04777
R04811 R04868 R04950 R05063 R05064 R05129 R05163 R05188
R05189 R05190 R05330 R05331 R05332 R05351 R05451 R05452
R05455 R05506 R05537 R05546 R05586 R05587 R05620 R05672
R05714 R05744 R05841 R05870 R05876 R05918 R06251 R06307
R06310 R06311 R06361 R06367 R06368 R06396 R06409 R06410
R06414 R06415 R06448 R06453 R06458 R06459 R06480 R06481
R06482 R06483 R06510 R06515 R06517 R06527 R06544 R06545
R06568 R06569 R06583 R06624 R06625 R06635 R06637 R06641
R06643 R06644 R06645 R06731 R06735 R06736 R06796 R06797
R06799 R06800 R06801 R06806 R06817 R06821 R06872 R06908
R06944 R06978 R06987 R06997 R07160 R07161 R07175 R07249
R07250 R07251 R07252 R07253 R07255 R07262 R07294 R07296
R07382 R07399 R07416 R07432 R07433 R07719 R07721 R07731
R07741 R07754 R07757 R07758 R07815 R07828 R07833 R07873
R07876 R07880 R07881 R07882 R07883 R07884 R07885 R07886
R07887 R07891 R07895 R07899 R07902 R07910 R07926 R07927
R07928 R07929 R07930 R07931 R07937 R07938 R07944 R07953
R07987 R07988 R07989 R08036 R08088 R08091 R08095 R08097
R08117 R08171 R08172 R08174 R08175 R08176 R08177 R08178
R08179 R08180 R08181 R08182 R08183 R08184 R08185 R08186
R08187 R08188 R08189 R08190 R08191 R08192 R08213 R08248
R08250 R08273 R08331 R08332 R08381 R08386 R08423 R08430
R08433 R08453 R08530 R08531 R08532 R08549 R08566 R08567
R08619 R08623 R08627 R08631 R08640 R08644 R08680 R08712
R08713 R08733 R08738 R08743 R08744 R08745 R08767 R08796
R08797 R08805 R08806 R08807 R08808 R08809 R08810 R08870
R08871 R08938 R08983 R09034 R09035 R09036 R09037 R09096
R09097 R09106 R09255 R09256 R09257 R09258 R09279 R09280
R09286 R09317 R09419 R09450 R09470 R09524 R09527 R09528
R09557 R09589 R09621 R09622 R09631 R09643 R09839 R09840
R09842 R09854 R09873 R10003 R10099 R10100 R10104 R10142
R10171 R10172 R10173 R10174 R10200 R10210 R10219 R10233
R10234 R10237 R10238 R10239 R10243 R10253 R10254 R10278
R10473 R10474 R10484 R10485 R10500 R10514 R10516 R10526
R10529 R10589 R10590 R10612 R10681 R10700 R10707 R10745
R10746 R10747 R10758 R10769 R10770 R10771 R10820 R10825
R10866 R10893 R10936 R10947 R10960 R10965 R10967 R10998
R11124 R11125 R11182 R11199 R11200 R11201 R11370 R11390
R11412 R11435 R11445 R11450 R11451 R11479 R11516 R11542
R11550 R11584 R11586 R11588 R11615 R11616 R11632 R11664
R11667 R11689 R11701 R11708 R11723 R11781 R11782 R11902
R11926 R11957 R11958 R12039 R12042 R12049 R12085 R12117
R12159 R12242 R12287 R12288 R12300 R12310 R12328 R12337
R12380 R12381 R12430 R12431 R12465 R12466 R12467 R12468
R12485 R12496 R12549 R12561 R12608 R12626 R12641 R12642
R12660 R12701 R12732 R12733 R12734 R12735 R12736 R12737
R12738 R12791 R12840 R12841 R12845 R12915 R12932 R12968
R12978 R13030 R13096 R13177 R13208 R13210 R13211 R13255
R13257 R13275 R13298 R13301 R13307 R13343 R13362
 » show all
Pathway
map00071  Fatty acid degradation
map00332  Carbapenem biosynthesis
map00770  Pantothenate and CoA biosynthesis
map01100  Metabolic pathways
map01110  Biosynthesis of secondary metabolites
map01240  Biosynthesis of cofactors
map04216  Ferroptosis
map04714  Thermogenesis
map04725  Cholinergic synapse
map04975  Fat digestion and absorption
map04977  Vitamin digestion and absorption
Module
M00120  Coenzyme A biosynthesis, pantothenate => CoA
M00914  Coenzyme A biosynthesis, archaea, 2-oxoisovalerate => 4-phosphopantoate => CoA
Network
nt06525  Ferroptosis
Enzyme
1.1.1.34        1.1.1.88        1.1.1.-         1.2.1.10        
1.2.1.17        1.2.1.18        1.2.1.25        1.2.1.27        
1.2.1.42        1.2.1.44        1.2.1.50        1.2.1.51        
1.2.1.52        1.2.1.57        1.2.1.58        1.2.1.75        
1.2.1.76        1.2.1.81        1.2.1.84        1.2.1.87        
1.2.1.104       1.2.1.105       1.2.1.-         1.2.3.6         
1.2.7.1         1.2.7.3         1.2.7.4         1.2.7.7         
1.2.7.8         1.2.7.11        1.2.7.-         1.8.1.10        
1.8.1.14        1.8.4.3         1.13.11.80      2.1.1.258       
2.3.1.1         2.3.1.2         2.3.1.3         2.3.1.4         
2.3.1.5         2.3.1.6         2.3.1.7         2.3.1.8         
2.3.1.9         2.3.1.10        2.3.1.11        2.3.1.12        
2.3.1.13        2.3.1.14        2.3.1.15        2.3.1.16        
2.3.1.17        2.3.1.18        2.3.1.19        2.3.1.20        
2.3.1.21        2.3.1.22        2.3.1.23        2.3.1.24        
2.3.1.25        2.3.1.26        2.3.1.27        2.3.1.28        
2.3.1.29        2.3.1.30        2.3.1.31        2.3.1.33        
2.3.1.34        2.3.1.36        2.3.1.37        2.3.1.38        
2.3.1.39        2.3.1.42        2.3.1.44        2.3.1.45        
2.3.1.46        2.3.1.47        2.3.1.48        2.3.1.50        
2.3.1.51        2.3.1.52        2.3.1.53        2.3.1.54        
2.3.1.57        2.3.1.58        2.3.1.59        2.3.1.60        
2.3.1.61        2.3.1.62        2.3.1.63        2.3.1.64        
2.3.1.65        2.3.1.66        2.3.1.67        2.3.1.68        
2.3.1.69        2.3.1.71        2.3.1.74        2.3.1.75        
2.3.1.76        2.3.1.78        2.3.1.79        2.3.1.80        
2.3.1.81        2.3.1.82        2.3.1.84        2.3.1.85        
2.3.1.86        2.3.1.87        2.3.1.89        2.3.1.93        
2.3.1.94        2.3.1.95        2.3.1.97        2.3.1.99        
2.3.1.100       2.3.1.102       2.3.1.105       2.3.1.106       
2.3.1.107       2.3.1.108       2.3.1.109       2.3.1.110       
2.3.1.111       2.3.1.112       2.3.1.113       2.3.1.114       
2.3.1.115       2.3.1.116       2.3.1.117       2.3.1.118       
2.3.1.121       2.3.1.123       2.3.1.125       2.3.1.126       
2.3.1.127       2.3.1.130       2.3.1.131       2.3.1.132       
2.3.1.133       2.3.1.136       2.3.1.137       2.3.1.138       
2.3.1.139       2.3.1.140       2.3.1.142       2.3.1.144       
2.3.1.145       2.3.1.146       2.3.1.150       2.3.1.151       
2.3.1.153       2.3.1.155       2.3.1.156       2.3.1.157       
2.3.1.159       2.3.1.160       2.3.1.161       2.3.1.162       
2.3.1.163       2.3.1.164       2.3.1.165       2.3.1.166       
2.3.1.167       2.3.1.168       2.3.1.169       2.3.1.170       
2.3.1.171       2.3.1.172       2.3.1.173       2.3.1.174       
2.3.1.175       2.3.1.176       2.3.1.177       2.3.1.178       
2.3.1.180       2.3.1.183       2.3.1.185       2.3.1.186       
2.3.1.188       2.3.1.189       2.3.1.190       2.3.1.192       
2.3.1.194       2.3.1.195       2.3.1.196       2.3.1.197       
2.3.1.198       2.3.1.199       2.3.1.201       2.3.1.202       
2.3.1.203       2.3.1.205       2.3.1.206       2.3.1.207       
2.3.1.208       2.3.1.209       2.3.1.210       2.3.1.211       
2.3.1.212       2.3.1.214       2.3.1.215       2.3.1.216       
2.3.1.217       2.3.1.218       2.3.1.219       2.3.1.220       
2.3.1.221       2.3.1.222       2.3.1.223       2.3.1.224       
2.3.1.225       2.3.1.226       2.3.1.227       2.3.1.228       
2.3.1.229       2.3.1.230       2.3.1.232       2.3.1.233       
2.3.1.235       2.3.1.236       2.3.1.237       2.3.1.239       
2.3.1.240       2.3.1.244       2.3.1.245       2.3.1.246       
2.3.1.248       2.3.1.249       2.3.1.250       2.3.1.252       
2.3.1.253       2.3.1.260       2.3.1.261       2.3.1.262       
2.3.1.263       2.3.1.264       2.3.1.265       2.3.1.266       
2.3.1.267       2.3.1.268       2.3.1.271       2.3.1.273       
2.3.1.276       2.3.1.278       2.3.1.279       2.3.1.280       
2.3.1.281       2.3.1.285       2.3.1.287       2.3.1.288       
2.3.1.289       2.3.1.290       2.3.1.291       2.3.1.297       
2.3.1.298       2.3.1.299       2.3.1.300       2.3.1.301       
2.3.1.302       2.3.1.303       2.3.1.304       2.3.1.306       
2.3.1.307       2.3.1.308       2.3.1.310       2.3.1.314       
2.3.1.316       2.3.1.320       2.3.1.321       2.3.1.322       
2.3.1.323       2.3.1.-         2.3.2.35        2.3.3.1         
2.3.3.2         2.3.3.3         2.3.3.4         2.3.3.5         
2.3.3.6         2.3.3.7         2.3.3.8         2.3.3.9         
2.3.3.10        2.3.3.11        2.3.3.12        2.3.3.13        
2.3.3.14        2.3.3.16        2.3.3.17        2.3.3.18        
2.3.3.19        2.3.3.20        2.3.3.21        2.3.3.-         
2.3.-.-         2.6.1.33        2.7.1.24        2.7.1.237       
2.7.8.7         2.7.8.-         2.8.3.-         3.1.2.1         
3.1.2.2         3.1.2.3         3.1.2.4         3.1.2.5         
3.1.2.10        3.1.2.11        3.1.2.17        3.1.2.18        
3.1.2.19        3.1.2.20        3.1.2.22        3.1.2.23        
3.1.2.25        3.1.2.27        3.1.2.28        3.1.2.29        
3.1.2.30        3.1.2.32        3.1.2.33        3.1.2.-         
3.2.1.-         3.6.1.77        4.1.3.36        4.1.3.-         
4.2.1.155       4.4.1.26        6.2.1.1         6.2.1.2         
6.2.1.3         6.2.1.4         6.2.1.5         6.2.1.6         
6.2.1.7         6.2.1.8         6.2.1.9         6.2.1.10        
6.2.1.11        6.2.1.12        6.2.1.13        6.2.1.14        
6.2.1.15        6.2.1.16        6.2.1.17        6.2.1.18        
6.2.1.23        6.2.1.24        6.2.1.25        6.2.1.26        
6.2.1.27        6.2.1.28        6.2.1.30        6.2.1.31        
6.2.1.32        6.2.1.33        6.2.1.34        6.2.1.36        
6.2.1.37        6.2.1.38        6.2.1.40        6.2.1.41        
6.2.1.42        6.2.1.43        6.2.1.44        6.2.1.48        
6.2.1.52        6.2.1.56        6.2.1.58        6.2.1.65        
6.2.1.75        6.2.1.76        6.2.1.-         6.3.2.50
 » show all
Brite
Compounds with biological roles [BR:br08001]
 Vitamins and cofactors
  Cofactors
   Coenzymes
    C00010  CoA
Other DBs
CAS: 85-61-0
PubChem: 3312
ChEBI: 15346
KNApSAcK: C00007258
PDB-CCD: COA[PDBj]
NIKKAJI: J192.630F
LinkDB
KCF data

ATOM        48
            1   N4y N    19.5936  -12.9137
            2   C1y C    19.0662  -15.1283
            3   C8y C    17.3673  -12.9137
            4   C8x C    19.5994  -11.6308
            5   O2x O    18.0119  -14.3666
            6   C1y C    18.6797  -16.3292
            7   C8y C    17.3673  -11.6308
            8   N5x N    16.2484  -13.5698
            9   N5x N    18.4864  -10.9805
            10  C1y C    16.9748  -15.1106
            11  C1y C    17.3790  -16.3292
            12  O1a O    19.3595  -17.2144
            13  C8y C    16.2484  -10.9922
            14  C8x C    15.1469  -12.9137
            15  C1b C    15.7856  -14.7356
            16  O2b O    16.7288  -17.2431
            17  N5x N    15.1469  -11.6308
            18  N1a N    16.2484   -9.7851
            19  O2b O    14.1097  -15.6318
            20  P1b P    15.3754  -17.2314
            21  P1b P    12.0070  -15.5851
            22  O1c O    15.3992  -15.9487
            23  O1c O    14.1977  -17.1908
            24  O1c O    15.4337  -18.5144
            25  O2c O    12.0070  -18.3501
            26  O1c O    12.0187  -14.2263
            27  O1c O    10.7997  -15.6318
            28  P1b P    12.0127  -21.0212
            29  O2b O    13.3427  -20.9920
            30  O1c O    12.0652  -22.5268
            31  O1c O    10.7356  -20.9978
            32  C1b C    14.4381  -20.3591
            33  C1d C    15.5453  -20.9920
            34  C1c C    16.6468  -20.3591
            35  C1a C    15.5278  -22.1284
            36  C1a C    15.5161  -19.7496
            37  C5a C    17.7540  -20.9920
            38  O1a O    16.6468  -19.0820
            39  N1b N    18.8554  -20.3591
            40  O5a O    17.7540  -22.1991
            41  C1b C    19.9568  -20.9920
            42  C1b C    21.0640  -20.3591
            43  C5a C    22.1654  -20.9920
            44  N1b N    23.2669  -20.3591
            45  O5a O    22.1654  -22.2691
            46  C1b C    24.3741  -20.9920
            47  C1b C    25.4755  -20.3534
            48  S1a S    26.5767  -20.9920
BOND        50
            1     2   1 1 #Up
            2     1   3 1
            3     1   4 1
            4     2   5 1
            5     2   6 1
            6     3   7 2
            7     3   8 1
            8     4   9 2
            9     5  10 1
            10    6  11 1
            11    6  12 1 #Down
            12    7  13 1
            13    8  14 2
            14   10  15 1 #Up
            15   11  16 1 #Down
            16   13  17 2
            17   13  18 1
            18   15  19 1
            19   16  20 1
            20   19  21 1
            21   20  22 1
            22   20  23 1
            23   20  24 2
            24   21  25 1
            25   21  26 1
            26   21  27 2
            27   25  28 1
            28   28  29 1
            29   28  30 1
            30   28  31 2
            31   29  32 1
            32   32  33 1
            33   33  34 1
            34   33  35 1
            35   33  36 1
            36   34  37 1
            37   34  38 1 #Up
            38   37  39 1
            39   37  40 2
            40   39  41 1
            41   41  42 1
            42   42  43 1
            43   43  44 1
            44   43  45 2
            45   44  46 1
            46   46  47 1
            47   47  48 1
            48    7   9 1
            49   10  11 1
            50   14  17 1

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